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72253

Sigma-Aldrich

Nickel(II) nitrate hexahydrate

purum p.a., crystallized, ≥97.0% (KT)

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About This Item

Linear Formula:
Ni(NO3)2 · 6H2O
CAS Number:
13478-00-7
Molecular Weight:
290.79
EC Number:
236-068-5
MDL number:
MFCD00149805
UNSPSC Code:
12352302
PubChem Substance ID:
329763936
NACRES:
NA.21

grade

purum p.a.

Assay

≥97.0% (KT)

form

crystals

quality

crystallized

mp

56 °C (lit.)

density

2.05 g/mL at 25 °C (lit.)

anion traces

chloride (Cl-): ≤50 mg/kg
sulfate (SO42-): ≤50 mg/kg

cation traces

Ca: ≤50 mg/kg
Cd: ≤50 mg/kg
Co: ≤500 mg/kg
Cu: ≤50 mg/kg
Fe: ≤50 mg/kg
K: ≤100 mg/kg
Na: ≤100 mg/kg
Pb: ≤50 mg/kg
Zn: ≤50 mg/kg

SMILES string

O.O.O.O.O.O.[Ni++].[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/2NO3.Ni.6H2O/c2*2-1(3)4;;;;;;;/h;;;6*1H2/q2*-1;+2;;;;;;

InChI key

AOPCKOPZYFFEDA-UHFFFAOYSA-N

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General description

Nickel(II) nitrate hexahydrate (Ni(NO3)2.6H2O) is a hydrated nickel(II) salt. Its thermal degradation has been investigated by thermogravimetric methods under quasi-isothermal conditions.

Application

Nickel(II) nitrate hexahydrate may be used as precursor for the synthesis of [Ni1/3Co1/3Mn1/3]O2 powders and Ni (II) oxide aerogels.

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1A - Eye Dam. 1 - Muta. 2 - Ox. Sol. 2 - Repr. 1B - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 1 Inhalation

Storage Class Code

5.1B - Oxidizing hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Monolithic nickel (II)-based aerogels using an organic epoxide: the importance of the counterion.
Gash AE, et al.
Journal of Non-Crystalline Solids, 350, 145-151 (2004)
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Biometals : an international journal on the role of metal ions in biology, biochemistry, and medicine, 26(1), 13-21 (2012-10-26)
Nickel is an ubiquitous transition metal that is industrially applied in many forms, which inevitably leads to a high degree of occupational and environmental exposure. Over-exposure to nickel can produce a variety of adverse effects on human health, including allergy
Synthesis and structural characterization of layered Li[Ni1/3Co1/3Mn1/3]O2 cathode materials by ultrasonic spray pyrolysis method.
Park SH, et al.
Electrochimica Acta, 49(4), 557-563 (2004)
Thermal decomposition of nickel nitrate hexahydrate, Ni(NO3)2?6H2O, in comparison to Co(NO3)2?6H2O and Ca(NO3)2?4H2O.
Brockner W, et al.
Thermochimica Acta, 456(1), 64-68 (2007)
Longwen Chen et al.
Journal of environmental sciences (China), 74, 58-70 (2018-10-21)
Processes based on non-thermal plasma (NTP) for indoor air treatment inevitably lead to the formation of toxic by-products such as ozone (O3) and nitrogen oxides (NOx). Adding a step of heterogeneous catalysis in series with NTP could allow for the
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