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Ethoxyquin-(ethoxy-d5)

PESTANAL®, analytical standard

Synonym(s):

6-(Ethoxy-d5)-1,2-dihydro-2,2,4-trimethylquinoline, Ethoxyquin-d5

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About This Item

Empirical Formula (Hill Notation):
C14D5H14NO
Molecular Weight:
222.34
UNSPSC Code:
41116107
PubChem Substance ID:
NACRES:
NA.24

grade

analytical standard

Quality Level

product line

PESTANAL®

Assay

≥98.0% (HPLC)

shelf life

limited shelf life, expiry date on the label

application(s)

agriculture

format

neat

storage temp.

2-8°C

SMILES string

CC1=CC(C)(C)NC2=CC=C(OC([2H])([2H])C([2H])([2H])[2H])C=C21

General description

Ethoxyquin-(ethoxy-d5) is an isotope labeled analog of ethoxyquin − an antioxidant used as a protectant/post-harvest fungicide in animal feed as well as agricultural products, wherein the ethoxy protons are replaced by deuterium.

Application

Isotope-labeled compounds are increasingly used in isotope dilution mass spectrometry (IDMS) for the quantitative analysis of pesticides. The major advantage of using this technique is that the isotope-labeled compounds have nearly the same physical properties as their non-labeled counterpart analogs, and thus show identical behavior during the workup and sample preparation process. This helps in overcoming the problems of matrix effects generally encountered in the usual LC-MS/GC-MS analysis, potentially resulting in biased results. By spiking the sample before workup with its isotope labeled analog, the loss of analyte that leads to matrix effects can be determined and compensated.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Precautionary Statements

Hazard Classifications

Acute Tox. 4 Oral

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


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Dissipation, metabolism and sorption of pesticides used in fruit-packaging plants: towards an optimized depuration of their pesticide-contaminated agro-industrial effluents
Karas P, et al.
The Science of the Total Environment, 530(8), 129-139 (2015)
Residue levels of ethoxyquin, imazalil, and iprodione in pears under cold-storage conditions
Lopez ML and Riba M
Journal of Agricultural and Food Chemistry, 47(8), 3228-3236 (1999)
Application of zirconium dioxide nanoparticle sorbent for the clean-up step in post-harvest pesticide residue analysis
Ucles A, et al.
Talanta, 144(8), 51-61 (2015)

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