808008
OsHCl(CO)[κ3-PyCH2NHC2H4NHPtBu2]
95%
Synonym(s):
Gusev osmium hydrogenation catalyst
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About This Item
Empirical Formula (Hill Notation):
C18H33ClN3OOsP
CAS Number:
Molecular Weight:
564.13
UNSPSC Code:
12352300
NACRES:
NA.22
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Application
OsHCl(CO)[κ3-PyCH2NHC2H4NHPtBu2] is a robust and highly efficient precatalyst for coupling amines with methanol and ethanol to afford formamides and acetamides. It possesses excellent carbonyl selectivity with an unique activity for acceptorless dehydrogenative coupling of alcohols to esters and amides.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Certificates of Analysis (COA)
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Chemoselective hydrogenation of carbonyl compounds and acceptorless dehydrogenative coupling of alcohols.
Spasyuk D, et al.
Journal of the American Chemical Society, 137(11), 3743-3746 (2015)
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