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776483

Sigma-Aldrich

8-Acetyl-5,6,7,8-tetrahydroquinoline

95%

Synonym(s):

8-Acetyl-5,6,7,8-tetrahydroquinoline

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About This Item

Empirical Formula (Hill Notation):
C11H13NO
CAS Number:
1146576-61-5
Molecular Weight:
175.23
UNSPSC Code:
12161600
NACRES:
NA.22

Assay

95%

form

liquid

reaction suitability

reagent type: ligand

refractive index

n20/D 1.568

density

1.107 g/mL at 25 °C

InChI

1S/C11H13NO/c1-8(13)10-6-2-4-9-5-3-7-12-11(9)10/h3,5,7,10H,2,4,6H2,1H3

InChI key

YCPXJTSSSPGZOE-UHFFFAOYSA-N

Application

Versatile ligand for CuI mediated room temperature C-N coupling reactions

Pictograms

Skull and crossbones
GHS06

Signal Word

Danger

Hazard Statements

H301,H315,H319,H335

Hazard Classifications

Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

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Deping Wang et al.
Chemical communications (Cambridge, England), (14), 1891-1893 (2009-03-26)
2-Pyridinyl beta-ketones were identified as new efficient ligands for CuI-catalysed N-arylation of aliphatic amines at room temperature with great selectivity and substrate scope tolerance.

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