Skip to Content
Merck
All Photos(2)

Key Documents

667110

Sigma-Aldrich

Dimethylphenylsilanol

95%

Sign Into View Organizational & Contract Pricing


About This Item

Linear Formula:
(C6H5)Si(OH)(CH3)2
CAS Number:
Molecular Weight:
152.27
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.22
Pricing and availability is not currently available.

Assay

95%

form

solid

refractive index

n20/D 1.514

density

0.975 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

C[Si](C)(O)c1ccccc1

InChI

1S/C8H12OSi/c1-10(2,9)8-6-4-3-5-7-8/h3-7,9H,1-2H3

InChI key

FDTBETCIPGWBHK-UHFFFAOYSA-N

Application

Dimethylphenylsilanol is an organosilanol that can be used:
  • As a coupling partner in the Pd(II) catalyzed Hiyama reaction for C5 C-H bond functionalization of 2,3-dihydropyridin-4(1H)-ones.[1]
  • To introduce dimethylphenylsilyl end group on highly branched poly(dimethylsiloxane) polymers.[2]
  • As a substrate in the Ru(0) catalyzed germasiloxanes synthesis by reacting with vinylgermanes.[3]

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

197.1 °F

Flash Point(C)

91.7 °C

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Direct Hiyama cross-coupling of enaminones with triethoxy (aryl) silanes and dimethylphenylsilanol
Bi L and Georg GI
Organic Letters, 13(20), 5413-5415 (2011)
Preparation and properties of novel hyperbranched poly(dimethylsiloxane)s
Kim K-M, et al.
Polymer Journal, 34(4), 275-279 (2002)
A new catalytic approach to germasiloxanes
Hreczycho G, et al.
Tetrahedron Letters, 52(1), 74-76 (2011)
Denmark, S. E.; Ober, M. H.
Aldrichimica Acta, 36, 75-75 (2003)

Articles

Pd-catalyzed cross-coupling of silicon compounds offers an alternative in synthetic chemistry.

Pd-catalyzed cross-coupling of silicon compounds offers an alternative in synthetic chemistry.

Pd-catalyzed cross-coupling of silicon compounds offers an alternative in synthetic chemistry.

Pd-catalyzed cross-coupling of silicon compounds offers an alternative in synthetic chemistry.

Questions

Reviews

No rating value

Active Filters

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service