56776
Trihexyltetradecylphosphonium dicyanamide
≥95% (qNMR)
Synonym(s):
Tetradecyltrihexylphosphonium dicyanamide
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About This Item
Linear Formula:
[CH3(CH2)5]3P[N(CN)2](CH2)13CH3
CAS Number:
Molecular Weight:
549.90
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
Assay
≥95% (qNMR)
density
0.90 g/mL at 20 °C (lit.)
functional group
amine
phosphine
SMILES string
N#C[N-]C#N.CCCCCCCCCCCCCC[P+](CCCCCC)(CCCCCC)CCCCCC
InChI
1S/C32H68P.C2N3/c1-5-9-13-17-18-19-20-21-22-23-24-28-32-33(29-25-14-10-6-2,30-26-15-11-7-3)31-27-16-12-8-4;3-1-5-2-4/h5-32H2,1-4H3;/q+1;-1
InChI key
DOMOOBQQQGXLGU-UHFFFAOYSA-N
Application
Trihexyltetradecylphosphonium dicyanamide is an ionic liquid that can be used:
- As an extraction solvent for the separation of organic compounds.[1]
- In the experiment to study the solubility of carbon dioxide[2] and binary gas mixtures in ionic liquids.[3]
- To prepare hybrid ionogels having electrochemical applications.[4]
- As a solvent for the extraction of aromatics from pyrolytic sugars.[5]
Caution
may become slightly turbid on storage
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
Storage Class Code
8A - Combustible corrosive hazardous materials
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Application of trihexyltetradecylphosphonium dicyanamide ionic liquid for various types of separations problems: Activity coefficients at infinite dilution measurements utilizing GLC method
Kabane B and Redhi GG
Fluid Phase Equilibria, 493, 181-187 (2019)
Solubility of CO2/CH4 gas mixtures in ionic liquids
Ramdin M, et al.
Fluid Phase Equilibria, 375, 134-142 (2014)
Photo-patternable hybrid ionogels for electrochromic applications
Kavanagh A, et al.
Journal of Materials Chemistry, 21(24), 8687-8693 (2011)
High pressure solubility of CO2 in non-fluorinated phosphonium-based ionic liquids
Ramdin M, et al.
Journal of Supercritical Fluids, 82, 41-49 (2013)
Viresh R Thamke et al.
Environmental pollution (Barking, Essex : 1987), 250, 567-577 (2019-04-27)
The present study deals with the cyto-genotoxicological impact of ionic liquids, 1-butyl-3-methylimidazolium bromide, trihexyl tetradecylphosphonium dicyanamide, 1-decyl-3-methylimidazolium tetrafluoroborate, benzyldimethyltetradecylammonium chloride, and 1-butyl-4-methylpyridinium chloride, on animal cells and their biodegradation. The long alkyl chain containing ionic liquids were found to be
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