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Assay
97%
form
liquid
refractive index
n20/D 1.4296 (lit.)
bp
157-160 °C (lit.)
density
0.805 g/mL at 25 °C (lit.)
SMILES string
CCN(CC)CCNC
InChI
1S/C7H18N2/c1-4-9(5-2)7-6-8-3/h8H,4-7H2,1-3H3
InChI key
MKDYQLJYEBWUIG-UHFFFAOYSA-N
General description
The Michael addition of N,N-Diethyl-N′-methylethylenediamine to nocathiacin was studied.
Application
N,N-Diethyl-N′-methylethylenediamine was used as a derivatization agent in the quantitative determination of isocyanates by capillary electrophoresis with tris(2,2′-bipyridyl)ruthenium(II) electrochemiluminescence (ECL).
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Flam. Liq. 3 - Skin Corr. 1B
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point(F)
105.8 °F - closed cup
Flash Point(C)
41 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Certificates of Analysis (COA)
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Organic reactions in frozen water: Michael addition of amines and thiols to the dehydroalanine side chain of nocathiacins.
Tetrahedron Letters, 45(5), 1059-1063 null
Electrophoresis, 30(22), 3926-3931 (2009-11-04)
CE with tris(2,2'-bipyridyl) ruthenium(II) (Ru(bpy)(3) (2+)) electrochemiluminescence (ECL) detection for the quantitative determination of isocyanates was first reported. Hexamethylene diisocyanate (HDI) and hexyl isocyanate (HI) were used as the model analytes. Commercially available N,N-diethyl-N'-methylethylenediamine was used as the derivatization reagent.
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