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301612

Sigma-Aldrich

9-Anthraldehyde oxime, predominantly syn

99%

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About This Item

Empirical Formula (Hill Notation):
C15H11NO
CAS Number:
Molecular Weight:
221.25
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Assay

99%

mp

162-164 °C (lit.)

SMILES string

O\N=C\c1c2ccccc2cc3ccccc13

InChI

1S/C15H11NO/c17-16-10-15-13-7-3-1-5-11(13)9-12-6-2-4-8-14(12)15/h1-10,17H/b16-10+

InChI key

HLGMTCSSRBPNOQ-MHWRWJLKSA-N

General description

Gallium triflate catalyzed dehydration of 9-anthraldehyde oxime to nitrile is reported.

Application

9-Anthraldehyde oxime was used in preparation of new triosmium cluster [Os3(CO)11(C14H9CN)].

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Synthesis and structural characterization of a triosmium carbonyl cluster containing a 9-anthracenecarbonitrile ligand derived from 9-anthraldehyde oxime.
Wong JS-Y, et al.
Inorganic Chemistry Communications, 6(6), 713-717 (2003)
Gallium (III) triflate catalyzed dehydration of aldoximes.
Yan P, et al.
Catalysis Letters, 101(3), 141-143 (2005)

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