295337
Trifluoromethane
≥98%
Synonym(s):
Fluoroform, HFC-23
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About This Item
Linear Formula:
CHF3
CAS Number:
Molecular Weight:
70.01
EC Number:
MDL number:
UNSPSC Code:
12142100
PubChem Substance ID:
NACRES:
NA.22
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Recommended Products
vapor density
2.43 (vs air)
vapor pressure
635 psi ( 21 °C)
Assay
≥98%
bp
−84 °C (lit.)
mp
−160 °C (lit.)
SMILES string
FC(F)F
InChI
1S/CHF3/c2-1(3)4/h1H
InChI key
XPDWGBQVDMORPB-UHFFFAOYSA-N
Packaging
Supplied in a carbon steel lecture bottle with a CGA180M/CGA110F needle valve installed.
Compatible with the following:
Compatible with the following:
- Aldrich® lecture-bottle station systems
- Aldrich® lecture-bottle gas regulators
Other Notes
See Technical Information Bulletin AL-151 Gas Regulators: Selection, Installation, and Operation
Legal Information
Aldrich is a registered trademark of Sigma-Aldrich Co. LLC
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Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Press. Gas Liquefied gas
Storage Class Code
2A - Gases
WGK
WGK 1
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Alessandro Zanardi et al.
Journal of the American Chemical Society, 133(51), 20901-20913 (2011-12-06)
We have found the first reaction of direct cupration of fluoroform, the most attractive CF(3) source for the introduction of the trifluoromethyl group into organic molecules. Treatment of CuX (X = Cl, Br, I) with 2 equiv of MOR (M
Sven P Fritz et al.
Organic letters, 14(24), 6370-6373 (2012-12-13)
CF(3)-substituted vinyl diphenylsulfonium triflate is an effective annulation reagent for the formation of α-CF(3) substituted, epoxide-fused heterocycles (pyrrolidines, piperidines, and tetrahydrofurans). This simple method affords a variety of valuable heterocyclic building blocks in a highly diastereoselective manner (dr >20:1).
Naleen B Jayaratna et al.
Inorganic chemistry, 52(4), 1691-1693 (2013-02-02)
Silver and copper ethylene adducts and the silver carbonyl complex of the tris(pyrazolyl)borate [HB(3,4,5-(CF(3))(3)Pz)(3)](-) (which is based on one of the most acidic pyrazoles known) have been synthesized. (13)C NMR resonance signals of metal-bound ethylene carbon atoms of [HB(3,4,5-(CF(3))(3)Pz)(3)]Ag(C(2)H(4)) and
Nicolas Susperregui et al.
The Journal of organic chemistry, 75(19), 6581-6587 (2010-08-31)
The mechanism of ring-opening of ε-caprolactone by methanol catalyzed by trifluoromethane and methane sulfonic acids has been studied computationally at the DFT level of theory. For both elementary steps, the sulfonic acid was predicted to behave as a bifunctional catalyst.
Naeem Iqbal et al.
The Journal of organic chemistry, 77(24), 11383-11387 (2012-11-22)
A method for trifluoromethylation of alkenes has been developed employing visible light photoredox catalysis with CF(3)I, Ru(Phen)(3)Cl(2), and DBU. This process works especially well for terminal alkenes to give alkenyl-CF(3) products with only E-stereochemistry. The mild reaction conditions enable the
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