Skip to Content
Merck
All Photos(2)

Documents

292788

Sigma-Aldrich

Potassium methoxide

95%

Synonym(s):

Potassium methylate

Sign Into View Organizational & Contract Pricing


About This Item

Linear Formula:
CH3OK
CAS Number:
Molecular Weight:
70.13
Beilstein:
3551544
EC Number:
MDL number:
UNSPSC Code:
12352107
PubChem Substance ID:
NACRES:
NA.22

Assay

95%

form

solid

SMILES string

[K+].C[O-]

InChI

1S/CH3O.K/c1-2;/h1H3;/q-1;+1

InChI key

BDAWXSQJJCIFIK-UHFFFAOYSA-N

Looking for similar products? Visit Product Comparison Guide

General description

Potassium methoxide is a basic nucleophile used in the dehalogenation of arylhalides.

Application

Potassium methoxide can be used:
  • As a methoxylating agent for methoxylation of bromo- and mesyloxyalkanes in the presence of an ionic liquid [bmim][BF4].
  • As a catalyst for the synthesis of dimethyl carbonate and methyl formate.
  • As a catalyst for the transesterification of sunflower oil for the production of biodiesel.

Pictograms

FlameCorrosion

Signal Word

Danger

Hazard Statements

Hazard Classifications

Self-heat. 1 - Skin Corr. 1B

Supplementary Hazards

Storage Class Code

4.2 - Pyrophoric and self-heating hazardous materials

WGK

WGK 2

Flash Point(F)

51.8 °F - closed cup

Flash Point(C)

11 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

The effect of Mo(CO)6 as a co-catalyst in the carbonylation of methanol to methyl formate catalyzed by potassium methoxide under CO, syngas and H2 atmospheres. HP-IR observation of the methoxycarbonyl intermediate of Mo(CO)6.
Jali S, et al.
J. Mol. Catal. A: Chem., 348(1-2), 63-69 (2011)
Oligoethylene Glycols as Highly Efficient Mutifunctional Promoters for Nucleophilic-Substitution Reactions
Vinod J H et al.
Chemistry?A European Journal , 18, 3918-3924 (2012)
General and practical potassium methoxide/disilane-mediated dehalogenative deuteration of (hetero) arylhalides
Xin W et al.
Journal of the American Chemical Society, 140, 10970-10974 (2018)
Synthesis of dimethyl carbonate from methanol and carbon dioxide using potassium methoxide as catalyst under mild conditions.
Cai Q, et al.
Catalysis Letters, 103(3-4), 225-228 (2005)
Integrated biodiesel production: a comparison of different homogeneous catalysts systems.
Vicente G, et al.
Bioresource Technology, 92(3), 297-305 (2004)

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service