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About This Item
Linear Formula:
F2C6H3CHO
CAS Number:
Molecular Weight:
142.10
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
Assay
98%
form
liquid
refractive index
n20/D 1.499 (lit.)
bp
64-65 °C/17 mmHg (lit.)
density
1.301 g/mL at 25 °C (lit.)
SMILES string
Fc1cccc(C=O)c1F
InChI
1S/C7H4F2O/c8-6-3-1-2-5(4-10)7(6)9/h1-4H
InChI key
WDBAXYQUOZDFOJ-UHFFFAOYSA-N
General description
The emission and absorption spectra of 2,3-difluorobenzaldehyde were studied.
Application
2,3-Difluorobenzaldehyde was used in the synthesis of aminophosphine.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point(F)
136.4 °F - closed cup
Flash Point(C)
58 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Certificates of Analysis (COA)
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Takashi Mino et al.
The Journal of organic chemistry, 71(19), 7346-7353 (2006-09-09)
N-Aryl indoline-type aminophosphines 1a-c were obtained in good yields by a nucleophilic aromatic substitution (S(N)Ar) reaction followed by silane reduction. Aminophosphine 1d was also prepared from 2,3-difluorobenzaldehyde (4) via dimethylhydrazone. Optical resolution of C(aryl)-N(amine) bond atropisomers was achieved using (S)-(+)-di-mu-chlorobis[2-[(dimethylamino)ethyl]phenyl-C(2),N]dipalladium(II)
Spectroscopy and dynamics of the excited singlet and triplet states of 2, 3-, 2, 4-and 2, 5-difluorobenzaldehyde vapors.
Itoh, T.
Journal of Molecular Spectroscopy, 257(2), 170-176 (2009)
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