The impurities present in this product have not been identified. The purity of this material is determined by GC and by Titration with Perchloric acid. Note that this product may contain up to 1% water content. This information is reported in the Certificate of Analysis. Please see the link below to review a sample or lot-specific Certificate:
https://www.sigmaaldrich.com/product/sial/e26266#product-documentation
E26266
Ethylenediamine
≥99%, liquid, ReagentPlus®
Synonym(s):
1,2-Diaminoethane
Sign In to View Organizational & Contract Pricing.
Select a Size
Change View
| Size/SKU | Availability | Price |
|---|
About This Item
Linear Formula:
NH2CH2CH2NH2
CAS Number:
Molecular Weight:
60.10
NACRES:
NA.21
PubChem Substance ID:
eCl@ss:
39030201
UNSPSC Code:
12352100
EC Number:
203-468-6
MDL number:
Beilstein/REAXYS Number:
605263
Assay:
≥99%
Form:
liquid
Pricing and availability is not currently available.
Product Name
Ethylenediamine, ReagentPlus®, ≥99%
agency
suitable for EPA 300
Quality Segment
vapor density
2.07 (vs air)
vapor pressure
10 mmHg ( 20 °C)
product line
ReagentPlus®
assay
≥99%
form
liquid
autoignition temp.
716 °F
expl. lim.
16 %
refractive index
n20/D 1.4565 (lit.)
bp
118 °C (lit.)
mp
8.5 °C (lit.)
solubility
H2O: soluble at
density
0.899 g/mL at 25 °C (lit.)
functional group
amine
SMILES string
NCCN
InChI
1S/C2H8N2/c3-1-2-4/h1-4H2
InChI key
PIICEJLVQHRZGT-UHFFFAOYSA-N
Gene Information
human ... FNTA(2339)
General description
Application
Ethylenediamine (1,2-Diaminoethane, DAE) can be used as a reagent to prepare various metal ion complexes. For instance, DAE reacts with chromium(II) salts forms a Cr(II)/DAE complex, which is used as an efficient reducing agent for the reduction of primary alkyl halides to alkanes, and aryl bromides or iodides to arenes. This complex is also used to reduce β-substituted alkyl halides and epoxides to alkenes.
DAE can also be used in the following reduction reactions:
DAE can also be used in the following reduction reactions:
- DAE/Borane (1:1) complex is used as a highly selective reducing agent for the conversion of cinnamaldehyde to cinnamyl alcohol.
- DAE/Li complex is used as an efficient reagent for the reduction of alkenes, aromatic hydrocarbons, phenols, and alcohols.
Ethylenediamine (en) has been used in the following process:
- Synthesis of nucleus pulposus (NP)-like collagen-glycosaminoglycans (CG) core.
- Surface modification of epoxy-activated cryogel.
- Alteration of the surface of carbon nanoparticles (CNPs) to generate CNPs-ethylene.
- Surface modification of triazolate-bridged metal-organic framework.
- As a solvent in the synthesis of ZnS (zinc sulfide) and ZnSe (zinc selenium) precursors by solvothermal process.
- As a reactant in the synthesis of Pd/C-ethylenediamine complex catalyst.
- As a chelating agent in the synthesis of β-Co(OH)2 nanocrystals.
- Synthesis of ethylenediamine-templated iron arsenates and fluoroarsenates.
- As a template agent and coordination agent in the synthesis of CdS (cadmium sulfide) nanocrystals.
Legal Information
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
1 of 1
This Item | |||
|---|---|---|---|
| description ReagentPlus®, ≥99% | description purified by redistillation, ≥99.5% | description analytical standard | description puriss. p.a., absolute, ≥99.5% (GC) |
| assay ≥99% | assay ≥99.5% | assay ≥99.8% (GC) | assay ≥99.5% (GC) |
| Quality Level 200 | Quality Level 200 | Quality Level 100 | Quality Level 200 |
| solubility H2O: soluble at | solubility ethanol: soluble(lit.), water: very soluble(lit.), water: miscible(lit.) | solubility H2O: soluble at | solubility H2O: soluble at |
| form liquid | form liquid | form - | form liquid |
| density 0.899 g/mL at 25 °C (lit.) | density 0.899 g/mL at 25 °C (lit.) | density 0.899 g/mL at 25 °C (lit.) | density 0.899 g/mL at 25 °C (lit.) |
| bp 118 °C (lit.) | bp 118 °C (lit.) | bp 118 °C (lit.) | bp 118 °C (lit.) |
Still not finding the right product?
Explore all of our products under Ethylenediamine
Signal Word
Danger
Hazard Codes
Precautionary Statements
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Flam. Liq. 3 - Resp. Sens. 1B - Skin Corr. 1B - Skin Sens. 1B
Storage Class
3 - Flammable liquids
WGK
WGK 1
Flash Point (°F)
100.4 °F - closed cup
Flash Point (°C)
38 °C - closed cup
PPE (personal protective equipment)
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Choose from one of the most recent versions:
Already Own This Product?
Find documentation for the products that you have recently purchased in the Document Library.
-
What are the 1% impurity in this compound?
1 answer-
Helpful?
-
-
Qual o método volumétrico realizado para a ánalise da reagente em questão??
1 answer-
The volumetric method used for analysis was titration with HClO4.
Helpful?
-
-
How can I determine the shelf life / expiration / retest date of this product?
1 answer-
If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdfHelpful?
-
-
How is shipping temperature determined? And how is it related to the product storage temperature?
1 answer-
Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
Helpful?
-
-
The concentration of the solution
1 answer-
This product is a neat or pure liquid with a reported density of 0.899 g/mL and a molecular weight of 60.10 g/mol. Assuming a 99.9% purity, the concentration is approximately 14.94 M. The molarity may be determined using the molecular weight, density, and lot specific purity as demonstrated in the calculation below:
(Density x 1000 x w/w% / Molecular Weight)Helpful?
-