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About This Item
Linear Formula:
HO2C13CH215NHCH2PO3H2
CAS Number:
Molecular Weight:
171.06
NACRES:
NA.24
PubChem Substance ID:
UNSPSC Code:
77101502
MDL number:
grade
analytical standard
Quality Level
product line
PESTANAL®
assay
≥99% (HPLC)
shelf life
limited shelf life, expiry date on the label
impurities
≤0.5% water
mp
230 °C (dec.) (lit.)
application(s)
agriculture
environmental
format
neat
mass shift
M+2
SMILES string
OC(=O)[13CH2][15NH]CP(O)(O)=O
InChI
1S/C3H8NO5P/c5-3(6)1-4-2-10(7,8)9/h4H,1-2H2,(H,5,6)(H2,7,8,9)/i1+1,4+1
InChI key
XDDAORKBJWWYJS-VFZPYAPFSA-N
General description
Glyphosate is one of the most used herbicides, especially in agriculture applications such as weed and vegetation control.
Application
Glyphosate-2-13C,15N may be used as a reference standard for the determination of glyphosate-2-13C,15N in saline natural water samples by high-performance liquid chromatography coupled to tandem mass spectrometry (HPLC-MS/MS). It may also be used as an internal standard for the analysis of glyphosate, aminomethylphosphonic acid and glufosinate in water samples by online solid-phase extraction (SPE) followed by HPLC/MS.
Analysis Note
13C enrichment ≥99 atom% based upon labeld precursor
15N enrichment ≥98 atom% based upon labeld precursor
15N enrichment ≥98 atom% based upon labeld precursor
Legal Information
PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany
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signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Dermal - Aquatic Chronic 2 - Eye Dam. 1
Storage Class
11 - Combustible Solids
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
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Methods of analysis by the US geological survey organic geochemistry research group-determination of glyphosate, aminomethylphosphonic acid, and glufosinate in water using online solid-phase extraction and high-performance liquid chromatography/mass spectrometry
Lee EA, et al.
Journal of Chromatography and Separation Techniques, 7(338), 2-2 (2002)
Optimization of an Enrichment and LC-MS/MS Method for the Analysis of Glyphosate and Aminomethylphosphonic Acid (AMPA) in Saline Natural Water Samples without Derivatization
Pupke D, et al.
Journal of Chromatography and Separation Techniques, 7(338), 2-2 (2016)
Lene Nørby Nielsen et al.
Environmental pollution (Barking, Essex : 1987), 233, 364-376 (2017-11-03)
Recently, concerns have been raised that residues of glyphosate-based herbicides may interfere with the homeostasis of the intestinal bacterial community and thereby affect the health of humans or animals. The biochemical pathway for aromatic amino acid synthesis (Shikimate pathway), which
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 90479-5MG | 04061833246962 |


