162574

Dimethylglyoxime

ACS reagent grade, ≥99%, liquid

• Synonym(s): DMG, 2,3-Butanedione dioxime, Diacetyldioxime
• Linear Formula: CH₃C(=NOH)C(=NOH)CH₃
• CAS Number: 95-45-4
• Molecular Weight: 116.12
• NACRES: NA.21
• PubChem Substance ID: 24849992
• UNSPSC Code: 12352100
• EC Number: 202-420-1
• MDL number: MFCD00002117
• Beilstein/REAXYS Number: 506731
• Assay: ≥99%
• Form: powder

Properties

• Product Name: Dimethylglyoxime, ACS reagent, ≥99%, powder
• grade: ACS reagent
• Quality Segment: 200
• assay: ≥99%
• form: powder
• impurities: ≤0.05% insol. Alcohol
• ign. residue: ≤0.05%
• mp: 240-241 °C (lit.)
• suitability: passes test for determination of nickel
• functional group: amine, oxime
• SMILES string: CC(=N/O)\C(C)=N\O
• InChI: 1S/C4H8N2O2/c1-3(5-7)4(2)6-8/h7-8H,1-2H3/b5-3+,6-4+
• InChI key: JGUQDUKBUKFFRO-GGWOSOGESA-N

Description

General description

Dimethylglyoxime(DMG) is a complexing ligand. Dimethylglyoxime forms a number of mixed ligand complexes with N-acetylglycine and various metals such as VO(IV), Ni(II), Zn(II), Pd(II), Cd(II) and Pb(II).

Application

Dimethylglyoxime (DMG) may be used as complexing agent for the quantification of metallic imprurities [cobalt(II) and nickel(II)] in brine (5.5mol/l aqueous solution of sodium chloride) by adsorptive stripping voltammetry. It may be used in the preparation of nickel dimethylglyoxime, a dye complex used for the fabrication of dye-sensitized solar cells.

Dimethylglyoxime may be used as a chelating agent for determining nickel ion in complexes by gravimetric, titrimetric or colorimetric analysis.

Safety Information

• pictograms: GHS02
• signalword: Warning
• hcodes: H228
• pcodes: P210 - P240 - P241 - P280 - P370 + P378
• Hazard Classifications: Flam. Sol. 2
• Storage Class: 4.1B - Flammable solid hazardous materials
• wgk: WGK 3
• ppe: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges