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Key Documents

772046

Sigma-Aldrich

Fmoc-D-His(Trt)-OH

97% (HPLC)

Synonym(s):

Fmoc-N(im)-trityl-D-histidine

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About This Item

Empirical Formula (Hill Notation):
C40H33N3O4
CAS Number:
Molecular Weight:
619.71
MDL number:
UNSPSC Code:
12352209
PubChem Substance ID:
NACRES:
NA.26

Quality Level

Assay

97% (HPLC)

form

powder or crystals

optical activity

[α]22/D -85.0°, c = 1% in chloroform

reaction suitability

reaction type: Fmoc solid-phase peptide synthesis

mp

141-146 °C

application(s)

peptide synthesis

functional group

Fmoc

storage temp.

2-8°C

SMILES string

OC(=O)[C@@H](Cc1cn(cn1)C(c2ccccc2)(c3ccccc3)c4ccccc4)NC(=O)OCC5c6ccccc6-c7ccccc57

InChI

1S/C40H33N3O4/c44-38(45)37(42-39(46)47-26-36-34-22-12-10-20-32(34)33-21-11-13-23-35(33)36)24-31-25-43(27-41-31)40(28-14-4-1-5-15-28,29-16-6-2-7-17-29)30-18-8-3-9-19-30/h1-23,25,27,36-37H,24,26H2,(H,42,46)(H,44,45)/t37-/m1/s1

InChI key

XXMYDXUIZKNHDT-DIPNUNPCSA-N

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Hazard Statements

Precautionary Statements

Hazard Classifications

Aquatic Chronic 4

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


Certificates of Analysis (COA)

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Seon-Yeong Kwak et al.
Amino acids, 46(12), 2777-2785 (2014-09-15)
Caffeic acid (CA) is one of the antioxidants found in plants, which protects vascular cells against vascular injuries from oxidative stress. In our previous study, caffeoyl-prolyl-histidine amide (CA-L-Pro-L-His-NH2; CA-PH; a CA derivative) was synthesized, which exhibited a strong antioxidant activity

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