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714941

Sigma-Aldrich

Chloro(cyclopentadienyl)[bis(diphenylphosphino)methane]ruthenium(II)

97%

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About This Item

Empirical Formula (Hill Notation):
C30H27ClP2Ru
CAS Number:
71397-33-6
Molecular Weight:
586.01
MDL number:
MFCD07782002
UNSPSC Code:
12161600
PubChem Substance ID:
329763328
NACRES:
NA.22

Quality Level

100

Assay

97%

form

powder

reaction suitability

core: ruthenium
reagent type: catalyst

mp

190-196 °C

SMILES string

Cl[Ru].[CH]1[CH][CH][CH][CH]1.C(P(c2ccccc2)c3ccccc3)P(c4ccccc4)c5ccccc5

InChI

1S/C25H22P2.C5H5.ClH.Ru/c1-5-13-22(14-6-1)26(23-15-7-2-8-16-23)21-27(24-17-9-3-10-18-24)25-19-11-4-12-20-25;1-2-4-5-3-1;;/h1-20H,21H2;1-5H;1H;/q;;;+1/p-1

InChI key

NFGZGIRSDQBCFT-UHFFFAOYSA-M

Application

Catalyst for:
  • Anti-Markovnikov hydration
  • β-alkylation with primary alcohols
  • Cyclization of terminal alkynals to cycloalkenes
  • Electrochemical oxidation of methanol
  • Hydration of 1-alkynes
  • Isomerization of allylic alcohols

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
MKCB1980V
MKBT2282V
MKBC5627V
MKBC5627

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