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Bis[tris(2-methylphenyl)phosphine]palladium

Name: Bis[tris(2-methylphenyl)phosphine]palladium
Brand: ALDRICH

97%, powder

Synonym(s):

Bis(tris(2-tolyl)phosphine)palladium, Pd[(o-tol)₃P]₂

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About This Item

Empirical Formula (Hill Notation):

C₄₂H₄₂P₂Pd

CAS Number:

69861-71-8

Molecular Weight:

715.15

UNSPSC Code:

12161600

PubChem Substance ID:

329763029

NACRES:

NA.22

MDL number:

MFCD12911908

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Properties

Product Name

Bis[tris(2-methylphenyl)phosphine]palladium, 97%

Quality Segment

100

assay

97%

form

powder

reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst

mp

220-225 °C

storage temp.

−20°C

SMILES string

[Pd].Cc1ccccc1P(c2ccccc2C)c3ccccc3C.Cc4ccccc4P(c5ccccc5C)c6ccccc6C

InChI

1S/2C21H21P.Pd/c2*1-16-10-4-7-13-19(16)22(20-14-8-5-11-17(20)2)21-15-9-6-12-18(21)3;/h2*4-15H,1-3H3;

InChI key

CUBIJGNGGJBNOC-UHFFFAOYSA-N

Description

Application

Catalyst for:

Palladium-catalyzed cross-coupling reactions and aminations
Kumada coupling
Arylation
Heck coupling

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This Item	667315	900701	759163
Sigma-Aldrich 711071 Bis[tris(2-methylphenyl)phosphine]palladium	Sigma-Aldrich 667315 Chloro(η²-P,C-tris(2,4-di-tert-butylphenyl)phosphite)(tricyclohexylphosphine)palladium(II)	Sigma-Aldrich 900701 P(t-Bu)₃Pd G4	Sigma-Aldrich 759163 P(o-tol)₃ Pd G2
reaction suitability core: palladium, reaction type: Cross Couplings, reaction type: Hiyama Coupling, reaction type: Sonogashira Coupling, reaction type: Suzuki-Miyaura Coupling, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Negishi Coupling, reagent type: catalyst, reaction type: Stille Coupling, reaction type: Heck Reaction	reaction suitability core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst	reaction suitability -	reaction suitability core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
assay 97%	assay -	assay 95%	assay 85%
form powder	form solid	form powder or crystals	form solid
Quality Level 100	Quality Level 100	Quality Level 100	Quality Level 100
storage temp. −20°C	storage temp. -	storage temp. -	storage temp. -
mp 220-225 °C	mp 176.7-187.1 °C	mp -	mp 159-191 °C (decomposition)

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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