695874
t-BuDavePhos
solid
Synonym(s):
2′-(Di-tert-butylphosphino)-N,N-dimethylbiphenyl-2-amine, t-Butyl DavePhos, 2-Di-tert-butylphosphino-2′-(N,N-dimethylamino)biphenyl, tBuDavePhos
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About This Item
Product Name
t-BuDavePhos,
form
solid
Quality Segment
reaction suitability
reagent type: ligand
reaction type: Arylations, reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reagent type: ligand
reaction type: C-X Bond Formation
mp
114-118 °C
functional group
phosphine
SMILES string
CN(C)c1ccccc1-c2ccccc2P(C(C)(C)C)C(C)(C)C
InChI
1S/C22H32NP/c1-21(2,3)24(22(4,5)6)20-16-12-10-14-18(20)17-13-9-11-15-19(17)23(7)8/h9-16H,1-8H3
InChI key
PHLPNEHPCYZBNZ-UHFFFAOYSA-N
Application
Dialkylbiaryl phosphine ligand often used for Pd-catalyzed reactions in a range of contexts.
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This Item | |||
|---|---|---|---|
| description - | description 1:1 THF adduct | description 97% | description - |
| reaction suitability reagent type: ligand | reaction suitability reaction type: Sonogashira Coupling, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Suzuki-Miyaura Coupling, reaction type: Negishi Coupling, reagent type: catalyst | reaction suitability reagent type: ligand | reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Negishi Coupling, reaction type: Stille Coupling, reaction type: Heck Reaction, reaction type: Suzuki-Miyaura Coupling, core: palladium, reaction type: Hiyama Coupling, reaction type: Sonogashira Coupling, reagent type: catalyst |
| form solid | form powder or crystals | form - | form powder or crystals |
| functional group phosphine | functional group phosphine | functional group phosphine | functional group phosphine |
| Quality Level 100 | Quality Level - | Quality Level 200 | Quality Level - |
| mp 114-118 °C | mp - | mp 121-124 °C (lit.) | mp >300 °C |
2′-(Di-tert-butylphosphino)-N,N-dimethylbiphenyl-2-amine | palladium cross-coupling reagent tBuDavePhos Pd G3, tBuDavePhos Pd G3 ligand to palladium ratio control, third generation tBuDavePhos Pd G3, highly soluble tBuDavePhos Pd G3 in organic solvents, tBuDavePhos Pd G3 chemical, tBuDavePhos Pd G3 precatalyst, efficient tBuDavePhos Pd G3 for palladium catalysis, Buchwald tBuDavePhos Pd G3 catalyst, tBuDavePhos Pd G3 for laboratory use, air stable tBuDavePhos Pd G3 reagent, moisture stable tBuDavePhos Pd G3 for cross-coupling, tBuDavePhos Pd G3 catalyst loading optimization, tBuDavePhos Pd G3 for organic synthesis, tBuDavePhos Pd G3 long-life solution reagent | - | 4th generation Buchwald precatalyst t-BuDavePhos Pd G4, t-BuDavePhos Pd G4 lab-grade, t-BuDavePhos Pd G4 chemical structure, t-BuDavePhos Pd G4 palladium catalyst, t-BuDavePhos Pd G4 for organic synthesis, t-BuDavePhos Pd G4 solvent compatibility, 1507403-97-5 t-BuDavePhos Pd G4, high purity t-BuDavePhos Pd G4 reagent, t-BuDavePhos Pd G4 cross-coupling catalyst, t-BuDavePhos Pd G4 for pharmaceutical applications, t-BuDavePhos Pd G4 reaction conditions |
Signal Word
Warning
Hazard Codes
Precautionary Statements
Hazard Classifications
Aquatic Chronic 4 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class
11 - Combustible Solids
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
PPE (personal protective equipment)
dust mask type N95 (US), Eyeshields, Gloves
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