693774

Chiralyst P1271

solid, Umicore

• Synonym(s): Bis(1,5-cyclooctadiene)iridium(I) tetrakis[3,5-bis(trifluoromethyl)phenyl]borate, Bis(cyclooctadiene)iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenyl)borate
• Linear Formula: (Ir(C₈H₁₂)₂)+ (B(C₈H₃F₆)₄)-
• CAS Number: 666826-16-0
• Molecular Weight: 1271.79
• UNSPSC Code: 12161600
• PubChem Substance ID: 329761619
• NACRES: NA.22
• MDL number: MFCD10567389

Properties

• Product Name: Chiralyst P1271, Umicore
• Quality Segment: 100
• form: solid
• reaction suitability: core: iridium, reagent type: catalyst; core: iridium
• greener alternative product characteristics: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Sustainability features
• SMILES string: [Ir+].C1CC=CCCC=C1.C2CC=CCCC=C2.FC(F)(F)c3cc(cc(c3)C(F)(F)F)[B-](c4cc(cc(c4)C(F)(F)F)C(F)(F)F)(c5cc(cc(c5)C(F)(F)F)C(F)(F)F)c6cc(cc(c6)C(F)(F)F)C(F)(F)F
• InChI: 1S/C32H12BF24.2C8H12.Ir/c34-25(35,36)13-1-14(26(37,38)39)6-21(5-13)33(22-7-15(27(40,41)42)2-16(8-22)28(43,44)45,23-9-17(29(46,47)48)3-18(10-23)30(49,50)51)24-11-19(31(52,53)54)4-20(12-24)32(55,56)57;2*1-2-4-6-8-7-5-3-1;/h1-12H;2*1-2,7-8H,3-6H2;/q-1;;;+1/b;2*2-1-,8-7-;
• InChI key: YQXKTVMJDKWGHI-AUUWQFPRSA-N

Description

General description

We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives. This iridium precatalyst is used for C-H activation, borylation, and silylation reactions, enabling selective and efficient transformations, offering a greener, potentially more sustainable option for advanced synthetic chemistry. Click here for more information.

Application

Catalyst for:

• Asymmetric hydrogenation reactions
• Directed cyclodehydration reaction
• Direct prenylation via C-H oxidative addition-allene insertion
• Double intramolecular hydroalkoxylation
• Intramolecular hydroamination reactions
• Directed C-H bond cleavage
• Imine vinylation reactions

Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis

Legal Information

Product of Umicore

Additional information available at www.pmc.umicore.com

Safety Information

• Storage Class: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable
• PPE (personal protective equipment): dust mask type N95 (US), Eyeshields, Gloves