692808

(R,R)-DACH-phenyl Trost ligand

95%

• Synonym(s): (1R,2R)-(+)-1,2-Diaminocyclohexane-N,N′-bis(2-diphenylphosphinobenzoyl)
• Empirical Formula (Hill Notation): C₄₄H₄₀N₂O₂P₂
• CAS Number: 138517-61-0
• Molecular Weight: 690.75
• NACRES: NA.22
• PubChem Substance ID: 329761529
• UNSPSC Code: 12352002
• MDL number: MFCD01631273

Properties

• Quality Segment: 100
• assay: 95%
• form: solid
• optical activity: [α]20/D +131°, c = 1 in methanol
• manufacturer/tradename: ECACC
• mp: 136-142 °C
• functional group: amide, phosphine
• SMILES string: O=C(N[C@@H]1CCCC[C@H]1NC(=O)c2ccccc2P(c3ccccc3)c4ccccc4)c5ccccc5P(c6ccccc6)c7ccccc7
• InChI: 1S/C44H40N2O2P2/c47-43(37-27-13-17-31-41(37)49(33-19-5-1-6-20-33)34-21-7-2-8-22-34)45-39-29-15-16-30-40(39)46-44(48)38-28-14-18-32-42(38)50(35-23-9-3-10-24-35)36-25-11-4-12-26-36/h1-14,17-28,31-32,39-40H,15-16,29-30H2,(H,45,47)(H,46,48)/t39-,40-/m1/s1
• InChI key: AXMSEDAJMGFTLR-XRSDMRJBSA-N

Description

Application

Asymmetirc allylic alkylation ligand.

Trost Ligands for Asymmetric Allylic Alkylation

Legal Information

Sold in collaboration with Dr. Reddy′s Laboratories for research purposes only. US Patent 5739396 applies.

Safety Information

• Storage Class: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable