668281

1-Hydroxytetraphenyl-cyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-μ-hydrotetracarbonyldiruthenium(II)

98%, solid

• Synonym(s): 2,4-Cyclopentadien-1-one, 2,3,4,5-tetraphenyl-, ruthenium complex, Shvo’s Catalyst, Tetracarbonyl-μ-hydro[(1,2,3,4,5-H)-1-hydroxylato-2,3,4,5-tetraphenyl-2,4-cyclopentadien-1-yl][(1,2,3,4,5-H)-1-hydroxy-2,3,4,5-tetraphenyl-2,4-cyclopentadien-1-yl]diruthenium
• Empirical Formula (Hill Notation): C₆₂H₄₂O₆Ru₂
• CAS Number: 104439-77-2
• Molecular Weight: 1085.13
• MDL number: MFCD03840556
• UNSPSC Code: 12161600
• PubChem Substance ID: 24884974
• NACRES: NA.22

Properties

• Product Name: 1-Hydroxytetraphenyl-cyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-μ-hydrotetracarbonyldiruthenium(II), 98%
• Quality Segment: 100
• assay: 98%
• form: solid
• reaction suitability: core: ruthenium, reagent type: catalyst
• mp: 223-227 °C
• SMILES string: [Ru][RuH].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].O[C]1[C]([C]([C]([C]1c2ccccc2)c3ccccc3)c4ccccc4)c5ccccc5.O=C6C(c7ccccc7)=C(c8ccccc8)C(c9ccccc9)=C6c%10ccccc%10
• InChI: 1S/C29H21O.C29H20O.4CO.2Ru.H/c2*30-29-27(23-17-9-3-10-18-23)25(21-13-5-1-6-14-21)26(22-15-7-2-8-16-22)28(29)24-19-11-4-12-20-24;4*1-2;;;/h1-20,30H;1-20H;;;;;;;
• InChI key: PISMVXYUJBWZFB-UHFFFAOYSA-N

Description

Application

Has found numerous applications as a versatile catalyst in organic synthesis, including the reduction of aldehydes and ketones to alcohols, bimolecular disproportionation reaction of aldehydes to esters, isomerization of allylic alcohols and oxidation of alcohols.

Shvo′s Catalyst

Safety Information

• Storage Class: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable