66770

Methylenediamine dihydrochloride

≥98.0% (AT)

• Synonym(s): Diaminomethane dihydrochloride
• Linear Formula: CH₂(NH₂)₂ · 2HCl
• CAS Number: 57166-92-4
• Molecular Weight: 118.99
• UNSPSC Code: 12352100
• NACRES: NA.22
• PubChem Substance ID: 57652063
• EC Number: 260-602-6
• Beilstein/REAXYS Number: 3664689
• MDL number: MFCD00040377
• Assay: ≥98.0% (AT)
• Form: solid

Properties

• Quality Segment: 200
• assay: ≥98.0% (AT)
• form: solid
• functional group: amine
• storage temp.: 2-8°C
• SMILES string: Cl.Cl.NCN
• InChI: 1S/CH6N2.2ClH/c2-1-3;;/h1-3H2;2*1H
• InChI key: QCYJCJJCNRIMNG-UHFFFAOYSA-N

Description

General description

Methylenediamine dihydrochloride, also known as Diaminomethane dihydrochloride is an organic compound that is often utilized as a reagent and slow ammonia-releasing agent during the synthesis of primary amides of peptides and amino acids from active esters.

Application

Methylenediamine dihydrochloride can be used as a reactant to synthesize:

• Poly(methylene biguanides) via polycondensation reaction with sodium dicyanamide in the presence of 1-butanol.
• Didodecanoylamides by reacting with (2S)-2-methyldodecanoyl chloride via acylation in the presence of sodium bicarbonate.

It can also be used as a hydrogen source in catalytic hydrogenation reactions.

Safety Information

• Storage Class: 11 - Combustible Solids
• wgk: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: Eyeshields, Gloves, type N95 (US)