665185

Bis(chlorogold(I)) bis(diphenylphosphino)methane

97%, solid

• Synonym(s): Methylenebis[diphenyl]phosphine gold complex
• Empirical Formula (Hill Notation): C₂₅H₂₂Au₂Cl₂P₂
• CAS Number: 37095-27-5
• Molecular Weight: 849.23
• UNSPSC Code: 12161600
• PubChem Substance ID: 24884721
• NACRES: NA.22
• MDL number: MFCD08705280

Properties

• Product Name: Bis(chlorogold(I)) bis(diphenylphosphino)methane, 97%
• Quality Segment: 100
• assay: 97%
• form: solid
• reaction suitability: core: gold, reagent type: catalyst
• greener alternative product characteristics: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Sustainability features
• SMILES string: Cl[Au][PH](C[PH]([Au]Cl)(c1ccccc1)c2ccccc2)(c3ccccc3)c4ccccc4
• InChI: 1S/C25H22P2.2Au.2ClH/c1-5-13-22(14-6-1)26(23-15-7-2-8-16-23)21-27(24-17-9-3-10-18-24)25-19-11-4-12-20-25;;;;/h1-20H,21H2;;;2*1H/q;2*+1;;/p-2
• InChI key: JNPUWTQJFLJEJC-UHFFFAOYSA-L

Description

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of the 12 Principles of Green Chemistry. This catalyst enables alkyne activation, cyclization, and C-H functionalization under mild conditions. Its superior selectivity enables elegant synthetic routes to complex heterocycles, reducing step count and waste. Click here for more information.

Application

Gold Catalysts — 21st Century ′Gold Rush′

Used for

• Pharmacological studies involving the anticancer activity of gold(I)-phosphine complexes as autophagy-inducing agents
• Triplet luminescent light emitting diodes with low turn-on voltage

Catalyst for:

• Stereoselective preparation of vinyltetrahydrofuran via intramolecular hydroalkoxylation
• Hydroamination and hydroalkoxylation reactions
• Asymmetric transition metal catalysis
• Gold(I) catalyzed intramolecular Schmidt reactions of homopropargyl azides

Safety Information

• Storage Class: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable
• PPE (personal protective equipment): Eyeshields, Gloves, type N95 (US)