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651494

Sigma-Aldrich

Gallium phosphide

(single crystal substrate), <111>, diam. × thickness 2 in. × 0.5 mm

Synonym(s):

Gallium monophosphide

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About This Item

Linear Formula:
GaP
CAS Number:
12063-98-8
Molecular Weight:
100.70
EC Number:
235-057-2
MDL number:
MFCD00016109
UNSPSC Code:
12352300
PubChem Substance ID:
24883833
NACRES:
NA.23

Quality Level

100

form

(single crystal substrate)

resistivity

~0.3 Ω-cm

diam. × thickness

2 in. × 0.5 mm

mp

1480 °C

density

4.13 g/mL at 25 °C

semiconductor properties

<111>

SMILES string

[P]#[Ga]

InChI

1S/Ga.P

InChI key

HZXMRANICFIONG-UHFFFAOYSA-N

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Physical properties

Thermal expansion: 5.3 x 10-6/°C
Undoped (N-type semiconductor), carrier concentration = 2-6 × 1016 cm-3, EPD < 3 × 105 cm-2, growth technique = LEC

Physical form

cubic (a = 5.4505Å)

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H319,H335

Hazard Classifications

Eye Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKBX6897V
MKBW8491V
10819AD

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I Cestier et al.
Optics express, 19(7), 6093-6099 (2011-04-01)
We describe dynamical four wave mixing (FWM) functionalities of an GaInP photonic crystal waveguide. A W1 waveguide was used to wavelength convert 100 ps pulses and for sampling a 10.56 Gbit/s data stream so as to time demultiplex it into
G Chen et al.
Nano letters, 8(5), 1341-1346 (2008-04-22)
We report on investigations of the interaction of light with nanoscale antennae made from crystalline GaP nanowires (NWs). Using Raman scattering, we have observed strong optical antenna effects which we identify with internal standing wave photon modes of the wire.
Dion McIntosh et al.
Optics express, 19(20), 19607-19612 (2011-10-15)
Gallium Phosphide (GaP) reach-through avalanche photodiodes (APDs) are reported. The APDs exhibited dark current less than a pico-ampere at unity gain. A quantum efficiency of 70% was achieved with a recessed window structure; this is almost two times higher than
I Cestier et al.
Optics express, 18(6), 5746-5753 (2010-04-15)
We report a large nonlinear response in a 1.3mm long GaInP photonic crystal waveguide. The wide band gap of GaInP (1.9 eV) ensures that no two photon absorption takes place for photons at 1.55mm improving the nonlinear performance. The nonlinearity
Kelley Rivoire et al.
Optics express, 17(25), 22609-22615 (2010-01-07)
We demonstrate second harmonic generation in photonic crystal nanocavities fabricated in the semiconductor gallium phosphide. We observe second harmonic radiation at 750 nm with input powers of only nanowatts coupled to the cavity and conversion effciency P(out)/P(2)(in,coupled)=430%/W. The large electronic
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