442178

p-Tolylmagnesium bromide solution

1.0 M in THF

• Synonym(s): 4-Methylphenylmagnesium bromide
• Linear Formula: CH₃C₆H₄MgBr
• CAS Number: 4294-57-9
• Molecular Weight: 195.34
• UNSPSC Code: 12352103
• NACRES: NA.22
• PubChem Substance ID: 24867733
• MDL number: MFCD00000040
• Beilstein/REAXYS Number: 636491

Properties

• Quality Segment: 100
• reaction suitability: reaction type: Grignard Reaction
• packaging: Sure/Seal^™ of
• concentration: 1.0 M in THF
• bp: 65-67 °C
• density: 1.002 g/mL at 25 °C
• SMILES string: Cc1ccc([Mg]Br)cc1
• InChI: 1S/C7H7.BrH.Mg/c1-7-5-3-2-4-6-7;;/h3-6H,1H3;1H;/q;;+1/p-1
• InChI key: ZRJNGFJIBZKXTP-UHFFFAOYSA-M

Description

Application

p-Tolylmagnesium bromide is a common Grignard reagent. It can also be used in a variety of cross-coupling reactions.

Legal Information

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

Safety Information

• pictograms: GHS02,GHS08,GHS05,GHS07
• signalword: Danger
• hcodes: H225,H314,H335,H336,H351
• Hazard Classifications: Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
• target_organs: Central nervous system, Respiratory system
• Storage Class: 3 - Flammable liquids
• flash_point_f: 1.4 °F
• flash_point_c: -17 °C
• ppe: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
• pcodes: P202 - P210 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• supp_hazards: EUH014,EUH019