438294

Tetrabutylphosphonium hydroxide solution

40 wt. % in H₂O

• Synonym(s): TBPH
• Linear Formula: (CH₃CH₂CH₂CH₂)₄P(OH)
• CAS Number: 14518-69-5
• Molecular Weight: 276.44
• UNSPSC Code: 12352000
• NACRES: NA.22
• PubChem Substance ID: 24867442
• MDL number: MFCD00068456
• Beilstein/REAXYS Number: 4826225
• Concentration: 40 wt. % in H₂O
• Form: liquid

Properties

• form: liquid
• Quality Segment: 100
• reaction suitability: core: phosphonium
• concentration: 40 wt. % in H₂O
• refractive index: n20/D 1.412
• density: 0.989 g/mL at 25 °C
• functional group: phosphine
• SMILES string: [OH-].CCCC[P+](CCCC)(CCCC)CCCC
• InChI: 1S/C16H36P.H2O/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;/h5-16H2,1-4H3;1H2/q+1;/p-1
• InChI key: DFQPZDGUFQJANM-UHFFFAOYSA-M

Description

Application

Tetrabutylphosphonium hydroxide (TBPH) can be used:

• To convert poorly water-soluble acidic APIs into TBP ionic liquids (IL).
• As a cation source in the synthesis of Good′s buffer ionic liquids (GB-ILs) via an acid−base neutralization reaction with Good′s buffer anions.
• To synthesize tetrabutylphosphonium acetate, which along with Cu₂O-nanoparticles forms an excellent catalyst system for protodecarboxylation reactions.

Safety Information

• pictograms: GHS05
• signalword: Danger
• hcodes: H314
• pcodes: P280 - P305 + P351 + P338 - P310
• Hazard Classifications: Skin Corr. 1B
• Storage Class: 8A - Combustible corrosive hazardous materials
• wgk: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter