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339350

Nickel(II) chloride

98%

Synonym(s):

Nickel dichloride, Nickel(2+) chloride, Nickelous chloride

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About This Item

Linear Formula:
NiCl2
CAS Number:
Molecular Weight:
129.60
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
231-743-0
MDL number:
Assay:
98%
Form:
powder
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Quality Segment

assay

98%

form

powder

reaction suitability

core: nickel, reagent type: catalyst

density

3.55 g/mL at 25 °C (lit.)

SMILES string

Cl[Ni]Cl

InChI

1S/2ClH.Ni/h2*1H;/q;;+2/p-2

InChI key

QMMRZOWCJAIUJA-UHFFFAOYSA-L

General description

Nickel(II) chloride 98% comes in a powder form and is a highly useful inorganic compound with a broad range of applications across various industries. Its relatively high purity makes it suitable for both industrial and laboratory settings. It is widely used in catalysis, electroplating, battery manufacturing, chemical synthesis, material science, dye and pigment production, and laboratory research.

Application

Nickel(II) chloride is utilized in the manufacturing of nickel-cadmium batteries, serving as a crucial component in the electrochemical reactions occurring within these rechargeable batteries. It is also suitable for use in theR&D activities of nickel-metal hydride (NiMH) batteries, which are used in various portable electronic devices and hybrid vehicles. In an experimet it has been found that Ni-NiCl2 composite cathode increased the output energy by ∼47% when the thermal batteries were used in weapons (working voltage >25 V), with a power density of up to 11.4 kW/kg. It is suitable as a catalyst or reagent in various organic synthesis reactions, such as cross-coupling reactions, amination, and cycloaddition reactions. In an experiment, it has been established that a wide variety of acyclic and cyclic dithioacetals can be prepared chemoselectively from the corresponding aldehydes by employing a catalytic amount of nickel(II) chloride in dry CH2Cl2–MeOH (5:1) at room temperature in good yields.

Features and Benefits

Some of the major advantages of this product is as a catalyst its high chemoselectivity, ease of operation, high yields, and also compatibility with other protecting groups. The compound′s capacity to aid in advanced material synthesis and promote environmental sustainability further highlights its value across various fields.
The vapor-phase co-reductions with other metal halides such as aluminum chloride (cat. no. 449598) by hydrogen results in finely divided intermetallics with applications as structural materials or compounds with useful thermoelectric, magnetic, and oxidation-resistance properties. Used in the synthesis of semiconducting metal-containing polymers in which the polypyrrole backbone has a conformational energy minimum and is nearly planar.
The vapor-phase co-reductions with other metal halides such as aluminum chloride (cat. no. 449598) by hydrogen results in finely divided intermetallics with applications as structural materials or compounds with useful thermoelectric, magnetic, and oxidation-resistance properties. Used in the synthesis of semiconducting metal-containing polymers in which the polypyrrole backbone has a conformational energy minimum and is nearly planar.

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form

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form

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form

powder

assay

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assay

99.99% trace metals basis

assay

99.9% trace metals basis

assay

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Quality Level

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Quality Level

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Quality Level

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density

3.55 g/mL at 25 °C (lit.)

density

3.55 g/mL at 25 °C (lit.)

density

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density

-

reaction suitability

reagent type: catalyst

reaction suitability

core: nickel

reaction suitability

core: nickel

reaction suitability

-


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Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1A Inhalation - Muta. 2 - Repr. 1B - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 1 Inhalation

Target Organs

Lungs

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

PPE (personal protective equipment)

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges



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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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