337331

Dichloro(1,5-cyclooctadiene)ruthenium(II), polymer

95%

• Synonym(s): (1,5-Cyclooctadiene)ruthenium(II) chloride, Ruthenium(II) chloride 1,5-cyclooctadiene complex
• Linear Formula: [Ru(COD)Cl₂]_n
• CAS Number: 50982-12-2
• Molecular Weight: 280.16 (as monomer)
• MDL number: MFCD00171304
• UNSPSC Code: 12161600
• NACRES: NA.22

Properties

• Quality Level: 200
• assay: 95%
• reaction suitability: core: ruthenium, reaction type: solution phase peptide synthesis, reagent type: catalyst
• greener alternative product characteristics: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• greener alternative category: , Aligned
• SMILES string: [Ru+2].[Cl-].[Cl-].C1CC=CCCC=C1
• InChI: 1S/C8H12.2ClH.Ru/c1-2-4-6-8-7-5-3-1;;;/h1-2,7-8H,3-6H2;2*1H;/q;;;+2/p-2
• InChI key: DMRVBCXRFYZCPR-UHFFFAOYSA-L

Description

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Versatile Ru catalyst precursor. Used with IMes to catalyze the dehydrogenative coupling of alcohols and amines to form amide bonds.

Versatile ruthenium catalyst precursor. Used with NHC ligand to catalyze greener amide bond formation by dehydrogenative coupling of amines and alcohols.

Amide Synthesis from Alcohols and Amines by the Extrusion of Dihydrogen

Safety Information

• pictograms: GHS07
• signalword: Warning
• hcodes: H315,H319
• pcodes: P264 - P280 - P302 + P352 - P305 + P351 + P338 - P332 + P313 - P337 + P313
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2
• Storage Class: 11 - Combustible Solids
• wgk: WGK 1
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: Eyeshields, Gloves