323233

Oxalyl bromide solution

2.0 M in methylene chloride

• Synonym(s): Ethanedioyl dibromide solution, NSC 96957
• Linear Formula: BrCOCOBr
• CAS Number: 15219-34-8
• Molecular Weight: 215.83
• NACRES: NA.22
• PubChem Substance ID: 24859231
• UNSPSC Code: 12352101
• MDL number: MFCD00000113
• Form: liquid

Properties

• form: liquid
• Quality Segment: 100
• reaction suitability: reagent type: oxidant
• concentration: 2.0 M in methylene chloride
• density: 1.517 g/mL at 25 °C
• functional group: acyl bromide
• SMILES string: BrC(=O)C(Br)=O
• InChI: 1S/C2Br2O2/c3-1(5)2(4)6
• InChI key: JAZLVNXWYDFQFE-UHFFFAOYSA-N

Description

Application

Used in synthetic applications of carbon-substituted iminium salts

Reactant for:

• Synthesis of mutasynthons added to cultures of A. pretiosum for mutasynthetic generation of ansamitocin derivatives
• Oxalic acid formation from hydroxyl radical substitutions
• Cyclization to produce CRF1 receptor antagonists
• Preparation, optical and electrochemical studies of thiophene end capped olig(2,3-alkylthieno[3,4-b]pyrazine)
• Asymmetrical synthesis of glycosyl chlorides and bromides

Safety Information

• pictograms: GHS08,GHS05,GHS07
• signalword: Danger
• hcodes: H314,H336,H351
• pcodes: P202 - P261 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Hazard Classifications: Carc. 2 - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
• target_organs: Central nervous system
• Storage Class: 6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
• wgk: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable