224421

sec-Butylmagnesium chloride solution

2.0 M in diethyl ether

• Synonym(s): 2-Butylmagnesium chloride, Chloro(1-methylpropyl)magnesium, sec-Butylchloromagnesium
• Linear Formula: CH₃CH₂CH(CH₃)MgCl
• CAS Number: 15366-08-2
• Molecular Weight: 116.87
• UNSPSC Code: 12352103
• NACRES: NA.22
• PubChem Substance ID: 24853437
• MDL number: MFCD00000467
• Beilstein/REAXYS Number: 3600265
• Concentration: 2.0 M in diethyl ether

Properties

• Quality Segment: 100
• reaction suitability: reaction type: Grignard Reaction
• packaging: Sure/Seal^™ of
• concentration: 2.0 M in diethyl ether
• density: 0.828 g/mL at 25 °C
• SMILES string: CCC(C)[Mg]Cl
• InChI: 1S/C4H9.ClH.Mg/c1-3-4-2;;/h3H,4H2,1-2H3;1H;/q;;+1/p-1
• InChI key: MJHZUYZQMNONPK-UHFFFAOYSA-M

Description

Application

sec-Butylmagnesium chloride solution is a Grignard reagent, it can be used in:

• Metal catalyzed cross-coupling reactions with non-activated aryl chlorides.
• The synthesis of various alkoxytrichlorosilanes by reacting with tetrachlorosilane and alcohols.

Legal Information

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

Safety Information

• pictograms: GHS02,GHS05,GHS07
• signalword: Danger
• hcodes: H225,H260,H302,H314,H336
• pcodes: P210 - P231 + P232 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
• target_organs: Central nervous system
• supp_hazards: EUH019
• Storage Class: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• wgk: WGK 1
• flash_point_f: -40.0 °F - closed cup
• flash_point_c: -40 °C - closed cup
• ppe: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
• Hazard Classifications: Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react. 1