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218324

(+)-Limonene oxide, mixture of cis and trans

97%

Synonym(s):

(3R)-6-Methyl-3-prop-1-en-2-yl-7-oxabicyclo[4.1.0]heptane, (4R)-1-Methyl-4-(1-methylethenyl)-7-oxabicyclo[4.1.0]heptane, (4R)-Limonene 1,2-epoxide

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About This Item

Empirical Formula (Hill Notation):
C10H16O
CAS Number:
Molecular Weight:
152.23
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
MDL number:
Assay:
97%
Form:
liquid
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Quality Segment

assay

97%

form

liquid

optical purity

ee: 98% (GLC)

refractive index

n20/D 1.466 (lit.)

bp

113-114 °C/50 mmHg (lit.)

density

0.929 g/mL at 25 °C (lit.)

functional group

ether

SMILES string

CC(=C)[C@@H]1CCC2(C)OC2C1

InChI

1S/C10H16O/c1-7(2)8-4-5-10(3)9(6-8)11-10/h8-9H,1,4-6H2,2-3H3/t8-,9?,10?/m1/s1

InChI key

CCEFMUBVSUDRLG-XNWIYYODSA-N

General description

Limonene oxide, also known as limonene 1,2-epoxide, is a monoterpene that can be prepared from limonene. It has antinociceptive and antitumoral activities and is used in many products like food additives, cosmetics, and perfumes.[1]

Application

(+)-Limonene oxide (mixture of cis and trans) undergoes biocatalytic resolution in the presence of epoxide hydrolase to form enantiomerically pure cis- and trans-limonene oxides.

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This Item
1776392145962118
assay

97%

assay

≥97.0% (sum of isomers, GC)

assay

-

assay

≥99.0% (sum of enantiomers, GC)

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100

refractive index

n20/D 1.466 (lit.)

refractive index

n20/D 1.467

refractive index

-

refractive index

n20/D 1.473

bp

113-114 °C/50 mmHg (lit.)

bp

-

bp

-

bp

176-177 °C (lit.)

density

0.929 g/mL at 25 °C (lit.)

density

0.930 g/mL at 20 °C (lit.)

density

-

density

0.842 g/mL at 20 °C (lit.)

form

liquid

form

liquid

form

liquid

form

-


Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

149.0 °F - closed cup

flash_point_c

65 °C - closed cup



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Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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