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15224

Bis(trifluoromethane)sulfonimide lithium salt

puriss., ≥99.0% (19F-NMR)

Synonym(s):

LiTFSI, Bis(trifluoromethylsulfonyl)amine lithium salt, Lithium bistrifluoromethanesulfonimidate

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About This Item

Linear Formula:
CF3SO2NLiSO2CF3
CAS Number:
Molecular Weight:
287.09
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
415-300-0
Beilstein/REAXYS Number:
6625414
MDL number:
Assay:
≥99.0% (19F-NMR)
Form:
powder
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grade

puriss.

Quality Segment

assay

≥99.0% (19F-NMR)

form

powder

impurities

≤1% water

mp

234-238 °C (lit.)

solubility

H2O: 10 mg/mL, clear, colorless

functional group

fluoro

SMILES string

[Li]N(S(=O)(=O)C(F)(F)F)S(=O)(=O)C(F)(F)F

InChI

1S/C2F6NO4S2.Li/c3-1(4,5)14(10,11)9-15(12,13)2(6,7)8;/q-1;+1

InChI key

QSZMZKBZAYQGRS-UHFFFAOYSA-N

Application

Bis(trifluoromethane)sulfonimide lithium salt (LiTFSI) is a source of lithium (Li+) ions that is extensively used as an organic electrolyte in lithium-ion batteries and capacitors. LiTFSI is also used as an additive to enhance the hole conductivity in perovskite and dye-sensitized solar cells.

Other Notes

Electrolyte suitable for lithium batteries showing very high conductivity

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This Item
544094282669449504
assay

≥99.0% (19F-NMR)

assay

99.95% trace metals basis

assay

96%

assay

-

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

-

solubility

H2O: 10 mg/mL, clear, colorless

solubility

-

solubility

-

solubility

-

form

powder

form

-

form

powder

form

-

mp

234-238 °C (lit.)

mp

234-238 °C (lit.)

mp

>300 °C (lit.)

mp

234-238 °C (lit.)

impurities

≤1% water

impurities

-

impurities

-

impurities

-


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signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1B - STOT RE 2 Oral

target_organs

Nervous system

Storage Class

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges



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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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