14694

Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate

• Synonym(s): Rhodium(I) tetrafluoroborate 1,5-Cyclooctadiene complex
• Empirical Formula (Hill Notation): C₁₆H₂₄BF₄Rh
• CAS Number: 35138-22-8
• Molecular Weight: 406.07
• NACRES: NA.22
• PubChem Substance ID: 57647189
• UNSPSC Code: 12161600
• MDL number: MFCD00075045

Properties

• composition: carbon content, 45.7-49.0%
• Quality Segment: 100
• reaction suitability: core: rhodium, reagent type: catalyst
• mp: ~190 °C (dec.)
• SMILES string: [Rh+].F[B-](F)(F)F.C1CC=CCCC=C1.C2CC=CCCC=C2
• InChI: 1S/2C8H12.BF4.Rh/c2*1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h2*1-2,7-8H,3-6H2;;/q;;-1;+1/b2*2-1-,8-7-;;
• InChI key: NBGSCPNNKGVTKU-QMDOQEJBSA-N

Description

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

Other Notes

Rhodium complex employed for preparing cationic COD-Rh complexes with phosphine ligands, e.g. for enantioselective hydrogenation; Hydrosilylation

Safety Information

• Pictograms: GHS08,GHS07
• Signal Word: Danger
• Hazard Codes: H302,H315,H317,H319,H334,H335
• Precautionary Statements: P261 - P264 - P280 - P301 + P312 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Oral - Eye Irrit. 2 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3
• Target Organs: Respiratory system
• Storage Class: 4.1B - Flammable solid hazardous materials
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable
• PPE (personal protective equipment): Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges