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932051

Sigma-Aldrich

2,6-Bis(3-(9H-carbazol-9-yl)phenyl)pyridine

≥99% (HPLC)

Synonym(s):

26DCzPPy

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About This Item

Empirical Formula (Hill Notation):
C41H27N3
CAS Number:
1013405-24-7
Molecular Weight:
561.67
MDL number:
MFCD20275106
UNSPSC Code:
12352005
NACRES:
NA.23

grade

sublimed grade

Quality Level

100

description

μh ≈ 1.0 x 10-5 cm2 V−1 s−1
μe ≈ 1.0 x 10-5 cm2 V−1 s−1

Assay

≥99% (HPLC)

loss

0.5% TGA, > 370 °C (weight loss)

solubility

chloroform: soluble
dichloromethane: soluble
toluene: soluble

fluorescence

λem 410 nm±10 nm in dichloromethane

Orbital energy

HOMO 6.05 eV 
LUMO 2.56 eV 

λ

in dichloromethane

UV absorption

λ: 239 nm±5 nm Amax
λ: 292 nm±5 nm Amax

SMILES string

C1(C2=CC=CC(N3C(C=CC=C4)=C4C5=C3C=CC=C5)=C2)=NC(C6=CC(N7C(C=CC=C8)=C8C9=C7C=CC=C9)=CC=C6)=CC=C1

InChI

1S/C41H27N3/c1-5-22-38-32(16-1)33-17-2-6-23-39(33)43(38)30-14-9-12-28(26-30)36-20-11-21-37(42-36)29-13-10-15-31(27-29)44-40-24-7-3-18-34(40)35-19-4-8-25-41(35)44/h1-27H

InChI key

UFWDOFZYKRDHPB-UHFFFAOYSA-N

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Application

2,6-Bis(3-(9H-carbazol-9-yl)phenyl)pyridine, also known as 26DCzPPy, is a solution-processable phosphorescent bipolar host material used for highly efficient optoelectronic devices such as OLED displays. It has a μh around 1.0 x 10-5 cm2 V−1 s−1 and a μe of about 1.0 x 10-5 cm2 V−1 s−1.
2,6-Bis(3-(9H-carbazol-9-yl)phenyl)pyridine, can be used in R&D in the field of organic electronics. It is commonly utilized as a host material in the emissive layer of organic light-emitting diodes (OLEDs) devices. provides good film-forming properties, high charge transport efficiency, and an excellent energy level match with various emissive dopants. It can be used as a hole-blocking or electron-blocking layer material in OLED devices. It can be used in organic photovoltaic (OPV) devices as an exciton-blocking layer. It helps in enhancing the charge separation and minimizing exciton recombination, thereby improving the power conversion efficiency of OPV devices.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
MKCS9643

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Pyridine-Containing Bipolar Host Materials for Highly Efficient Blue Phosphorescent OLEDs
Su, Shi-Jia, et al.
Chemistry of Materials, 20, 1691-1693 (2008)
High-efficiency red, green and blue phosphorescent homojunction organic light-emitting diodes based on bipolar host materials
Cai, Chao, et al.
Organic Electronics, 12, 843-850 (2011)
Interfacial TADF Exciplex as a Tool to Localize Excitons, Improve Efficiency, and Increase OLED Lifetime
Colella, M. et al.
ACS Applied Materials & Interfaces, 10, 40001-40007 (2018)
Blue and white phosphorescent organic light emitting diode performance improvement by confining electrons and holes inside double emitting layers
Tsai, Yu-Sheng, et al.
Journal of Luminescence, 153, 312-316 (2014)
Soluble processed low-voltage and high efficiency blue phosphorescent organic light-emitting devices using small molecule host systems
Doh J., et al.
Organic Electronics, 13, 586-592 (2012)

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