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Sigma-Aldrich

Basolite® F300

greener alternative

produced by BASF

Synonym(s):

Fe-BTC, Iron 1,3,5-benzenetricarboxylate

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About This Item

Empirical Formula (Hill Notation):
C9H3FeO6
CAS Number:
1195763-37-1
Molecular Weight:
262.96
MDL number:
MFCD11656051
UNSPSC Code:
26111700
PubChem Substance ID:
329761369
NACRES:
NA.23
Pricing and availability is not currently available.

grade

produced by BASF

Quality Level

100

form

solid

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

surface area

120-190 m2/g

bulk density

0.16‑0.35 g/cm3

greener alternative category

, Enabling

SMILES string

O=C1O[Fe]2OC(=O)c3cc1cc(c3)C(=O)O2

InChI

1S/C9H6O6.Fe/c10-7(11)4-1-5(8(12)13)3-6(2-4)9(14)15;/h1-3H,(H,10,11)(H,12,13)(H,14,15);/q;+3/p-3

InChI key

UTYFBNKMZYRAFO-UHFFFAOYSA-K

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General description

Basolite®F300 (Fe-BTC) is a porous metal organic framework (MOF) that is used as a highly active catalyst for Lewis acid reactions such as acetalization of aldehydes and aldol condensation. It has a hybrid supertetrahedral build up from oxocentered trimmers of iron(III) octahedron that are connected by trimesate anions.[1]
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

Fe-BTC based MOF can be used in greener applications such as energy storage through lithium ion batteries. It can also be used in the supercritical adsorption of CO2.[2][3][4]

Legal Information

Basolite is a registered trademark of BASF SE

Pictograms

Health hazardExclamation mark
GHS08,GHS07

Signal Word

Warning

Hazard Statements

H302,H315,H319,H371

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 2

Target Organs

Eyes,Central nervous system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
STBJ5843
STBD9968V
S61151V
S61151
S58688

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A combined computational and experimental study of high pressure and supercritical CO2 adsorption on Basolite MOFs
Deniz E, et al.
Microporous and Mesoporous Materials : The Official Journal of the International Zeolite Association, 175(115), 34-42 (2013)
Direct synthesis, structural features, and enhanced catalytic activity of the basolite F300-like semiamorphous Fe-BTC framework
Sanchez-Sanchez M, et al.
Crystal Growth & Design, 15(9), 4498-4506 (2015)
Vijaya Ravinayagam et al.
Saudi journal of biological sciences, 27(7), 1726-1736 (2020-06-23)
Drug resistant bacteria affects millions worldwide and remains a serious threat to health care system. The study reports the first application of hybrid nanocomposites based on zeolitic imidazolate framework-8 (ZIF-8) with MFI structured zeolite Ti-ZSM-5 (TiZ5) and mesoporous carbon (MC).
Comparison of porous iron trimesates basolite F300 and MIL-100 (Fe) as heterogeneous catalysts for lewis acid and oxidation reactions: roles of structural defects and stability
Dhakshinamoorthy A, et al.
ACS Catalysis, 2(10), 2060-2065 (2012)
Facile synthesis of the Basolite F300-like nanoscale Fe-BTC framework and its lithium storage properties
Hu X, et al.
Royal Society of Chemistry Advances, 6(115), 114483-114490 (2016)
View All Related Papers

Articles

Metal Organic Frameworks (MOFs)

Metal-organic frameworks (MOFs) are porous, crystalline materials composed of metal ions bound by organic ligands.

Metal Organic Frameworks (MOFs)

Metal-organic frameworks (MOFs) are porous, crystalline materials composed of metal ions bound by organic ligands.

Metal Organic Frameworks (MOFs)

Metal-organic frameworks (MOFs) are porous, crystalline materials composed of metal ions bound by organic ligands.

Metal Organic Frameworks (MOFs)

Metal-organic frameworks (MOFs) are porous, crystalline materials composed of metal ions bound by organic ligands.

Questions

1–3 of 3 Questions  

  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  3. 物理的性質（例えば比表面積）の安定しているサンプルでしょうか？ 経時変化や劣化などはしないでしょうか？

    1 answer

    1. If the product is stored according to the SDS (i.e. tightly closed and dry), there should not be changes to the pore structure over time.

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