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Key Documents

62528

Sigma-Aldrich

Lithium hydroxide monohydrate

BioUltra, ≥99.0% (T)

Synonym(s):

LiOH · H2O, Lithium hydroxide, Lithium hydroxide hydrate

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About This Item

Linear Formula:
LiOH · H2O
CAS Number:
Molecular Weight:
41.96
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.25

product line

BioUltra

Assay

≥99.0% (T)

form

solid

impurities

insoluble matter, passes filter test

pH

~12 (25 °C, 1 M in H2O)

solubility

H2O: 1 M at 20 °C, clear, colorless

anion traces

chloride (Cl-): ≤50 mg/kg
sulfate (SO42-): ≤100 mg/kg

cation traces

Al: ≤20 mg/kg
As: ≤0.2 mg/kg
Ba: ≤5 mg/kg
Bi: ≤5 mg/kg
Ca: ≤50 mg/kg
Cd: ≤5 mg/kg
Co: ≤5 mg/kg
Cr: ≤5 mg/kg
Cu: ≤5 mg/kg
Fe: ≤5 mg/kg
K: ≤200 mg/kg
Mg: ≤5 mg/kg
Mn: ≤5 mg/kg
Mo: ≤5 mg/kg
Na: ≤50 mg/kg
Ni: ≤5 mg/kg
Pb: ≤5 mg/kg
Sr: ≤5 mg/kg
Zn: ≤5 mg/kg

λ

1 M in H2O

UV absorption

λ: 260 nm Amax: 0.02
λ: 280 nm Amax: 0.02

SMILES string

[Li+].O.[OH-]

InChI

1S/Li.2H2O/h;2*1H2/q+1;;/p-1

InChI key

GLXDVVHUTZTUQK-UHFFFAOYSA-M

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Application

Lithium hydroxide, an alkaline activator/catalyst of synthetic processes, may be used in the formation of polycrystalline Li2O nanowires.

Other Notes

Titrant in the procedure for the cleavage of Asn-Gly bonds with hydroxylamine

Pictograms

CorrosionExclamation mark

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Cleavage at Asn-Gly bonds with hydroxylamine.
P Bornstein et al.
Methods in enzymology, 47, 132-145 (1977-01-01)
Jinyoung Jeong et al.
Advanced materials (Deerfield Beach, Fla.), 24(15), 1999-2003 (2012-03-21)
Highly water-soluble and color-tunable photoluminescent fullerene nanoparticles are synthesized by using tetraethylene glycol (TEG) and lithium hydroxide as a catalyst. The maximum PL emission changes depend on the contents of the remaining π-conjugation in oxidized C(60), which is partially covalently
Muhammad Ayoub et al.
Bioresource technology, 112, 308-312 (2012-03-23)
The synthesis of oxygenated fuel additives via solvent freebase-catalyzed etherification of glycerol is reported. The products of glycerol etherification arediglycerol (DG) and triglycerol (TG) with DG being the favorable one. The catalytic activity of different homogeneous alkali catalysts (LiOH, NaOH
Z T Yao et al.
Journal of hazardous materials, 170(2-3), 639-644 (2009-06-06)
The zeolite Li-ABW was synthesized by fusion method using fly ash as raw material. It comprised alkaline fusion followed by hydrothermal treatment in LiOH x H2O medium. Crystallinity of zeolite as high as 97.8% was attained under the following conditions:
Cheng Guo et al.
Journal of the American Society for Mass Spectrometry, 23(7), 1191-1201 (2012-05-03)
Collision-induced dissociation (CID) of Li(+) adducts of three sets of compounds that contains an amide bond, including 2-(4, 6-dimethoxypyrimidin-2-ylsulfanyl)-N-phenylbenzamide, its derivatives and simpler structures was investigated by electrospray ionization tandem mass spectrometry (ESI-MS/MS). Observed fragment ions include those that reflect

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