Skip to Content
Merck
All Photos(5)

Key Documents

View All Documentation

912573

Sigma-Aldrich

High surface area conducting polypyrrole

greener alternative

Synonym(s):

3D cross-linked polypyrrole, doped by phytic acid, Doped polypyrrole hydrogels, PPy

Sign Into View Organizational & Contract Pricing
All Photos(5)

About This Item

UNSPSC Code:
12352103
NACRES:
NA.23

description

Electrochemical activity: see attached CV result

Quality Level

100

form

solid

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

color

black

solubility

soluble (swell into hydrogel but does not dissolve in water)

greener alternative category

Enabling,

Related Categories

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of the 12 Principles of Green Chemistry. This product is used in energy conversion and storage, thus has been enhanced for energy efficiency. Click here for more information.

Application

Three-dimensionally cross-linked polypyrrole (3D cross-linked polypyrrole) is a conductive powder made by crosslinking polypyrrole with a dopant molecule - phytic acid. It can form intrinsically conductive hydrogels with a hierarchically porous microstructure. Its porosity promotes transport of electrons and facilitates the diffusion of ions and other small molecules. Its flexibility can also help accommodate the strain caused by volume change during electrochemical cycling. Together with the advantage of high surface area, and biocompatibility, this material provides the feasibility for fabricating flexible, lightweight, energy and bioelectronic devices. Three-dimensionally cross-linked polypyrrole can also been derived into porous carbon nanomaterials via post thermal treatment and activation. The resulted carbon matrix has maintained the hierarchical nanostructure of 3D cross-linked polypyrrole and has been demonstrated as an effective additive to improve energy storage and conversion performance of other electrochemically active materials.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number
MKCR4814
MKCM2308

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Designing Hierarchically Nanostructured Conductive Polymer Gels for Electrochemical Energy Storage and Conversion.
Shi Y,et al.
Chemistry of Materials, 28(8), 2466-2477 (2016)
Graeme S A, et al.
Journal of Power Sources, 196, 1-12 (2011)
Nanostructured conductive polypyrrole hydrogels as high-performance, flexible supercapacitor electrodes.
Shi Y,et al.
Journal of Material Chemistry A, 2, 6086?6091-6086?6091 (2014)
Borui Liu et al.
Nano letters, 13(7), 3414-3419 (2013-06-22)
Silicon is considered one of the most promising anode materials for high-performance Li-ion batteries due to its 4200 mAh/g theoretical specific capacity, relative abundance, low cost, and environmental benignity. However, silicon experiences a dramatic volume change (∼300%) during full charge/discharge

Articles

Recent Developments in Silicon Anode Materials for High Performance Lithium-Ion Batteries

Recent demand for electric and hybrid vehicles, coupled with a reduction in prices, has caused lithium-ion batteries (LIBs) to become an increasingly popular form of rechargeable battery technology.

Stretchable Electroluminescent Devices

Self-healing soft electronic materials offer potential cost savings and reduced electronic waste.

Stretchable Electroluminescent Devices

Self-healing soft electronic materials offer potential cost savings and reduced electronic waste.

Stretchable Electroluminescent Devices

Self-healing soft electronic materials offer potential cost savings and reduced electronic waste.

See All

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service