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213950

Vinyltrimethylsilane

97%

Synonym(s):

Trimethyl(vinyl)silane, (Trimethylsilyl)ethylene, Ethenyltrimethylsilane

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About This Item

Linear Formula:
(CH3)3SiCHCH2
CAS Number:
Molecular Weight:
100.23
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
EC Number:
212-042-9
Beilstein/REAXYS Number:
956572
MDL number:
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vapor pressure

4.44 psi ( 20 °C)

Quality Level

assay

97%

form

liquid

impurities

<3% tetrahydrofuran

refractive index

n20/D 1.391 (lit.)

bp

55 °C (lit.)

density

0.684 g/mL at 25 °C (lit.)

SMILES string

C[Si](C)(C)C=C

InChI

1S/C5H12Si/c1-5-6(2,3)4/h5H,1H2,2-4H3

InChI key

GCSJLQSCSDMKTP-UHFFFAOYSA-N

Application

Used for the preparation of trimethylsilylethyl sulfoxides which in the presence of fluoride ion generate sulfenate nucleophiles.

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197734217069359998
assay

97%

assay

99%

assay

98%

assay

98%

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

200

density

0.684 g/mL at 25 °C (lit.)

density

0.873 g/mL at 25 °C (lit.)

density

0.715 g/mL at 25 °C (lit.)

density

1.167 g/mL at 25 °C (lit.)

bp

55 °C (lit.)

bp

168-170 °C (lit.)

bp

112-114 °C (lit.)

bp

50-51 °C/52 mmHg (lit.)

refractive index

n20/D 1.391 (lit.)

refractive index

n20/D 1.491 (lit.)

refractive index

n20/D 1.422 (lit.)

refractive index

n20/D 1.466 (lit.)

vapor pressure

4.44 psi ( 20 °C)

vapor pressure

-

vapor pressure

-

vapor pressure

-


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signalword

Danger

Hazard Classifications

Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2

supp_hazards

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

-11.2 °F

flash_point_c

-24 °C

ppe

Eyeshields, Faceshields, Gloves



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Seco-steroids. I. 15,16-Secoprogesterone.
N S Crossley
Journal of the Chemical Society. Perkin transactions 1, 13, 2491-2495 (1971-01-01)
J. Mol. Catal., 90, 125-125 (1994)
Synthesis, 1315-1315 (2007)



Global Trade Item Number

SKUGTIN
213950-100G04061838347183
213950-25G04061838773012
213950-5G04061837909887

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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