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Key Documents

115819

Sigma-Aldrich

2,2′-Biphenol

99%

Synonym(s):

2,2′-Biphenyldiol, 2,2′-Dihydroxybiphenyl, 2,2′-Diphenol

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About This Item

Linear Formula:
HOC6H4C6H4OH
CAS Number:
Molecular Weight:
186.21
Beilstein:
1638363
EC Number:
MDL number:
UNSPSC Code:
12162002
PubChem Substance ID:
NACRES:
NA.23

Quality Level

Assay

99%

form

solid

bp

315 °C (lit.)

mp

108-110 °C (lit.)

SMILES string

Oc1ccccc1-c2ccccc2O

InChI

1S/C12H10O2/c13-11-7-3-1-5-9(11)10-6-2-4-8-12(10)14/h1-8,13-14H

InChI key

IMHDGJOMLMDPJN-UHFFFAOYSA-N

Storage Class Code

11 - Combustible Solids

WGK

WGK 2

Flash Point(F)

309.2 °F - closed cup - (External MSDS)

Flash Point(C)

154 °C - closed cup - (External MSDS)

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Atsushi Kuwahara et al.
The Journal of organic chemistry, 70(2), 413-419 (2005-01-18)
The double N-arylation of primary amines with 2,2'-biphenylylene ditriflates was investigated for the synthesis of multisubstituted carbazoles. Palladium complexes supported by 2-dicyclohexylphosphino-2'-methylbiphenyl or Xantphos [4,5-bis(diphenylphosphino)-9,9-dimethylxanthene] were found to be efficient catalysts for the reaction. The catalysts allow the use of
Zengqi Xie et al.
Organic letters, 12(14), 3204-3207 (2010-06-22)
Facile nucleophilic substitution of two chlorine atoms by 2,2'-biphenol at one of the two bay areas (1,12- and 6,7-positions) of core-tetrachlorinated perylene bisimide afforded a novel, completely desymmetrized perylene bisimide building block, which could be further functionalized by substitution of
H P Kohler et al.
Journal of bacteriology, 175(6), 1621-1628 (1993-03-01)
Cells of Pseudomonas sp. strain HBP1 grown on 2-hydroxy- or 2,2'-dihydroxybiphenyl contain NADH-dependent monooxygenase activity that hydroxylates 2,2'-dihydroxybiphenyl. The product of this reaction was identified as 2,2',3-trihydroxybiphenyl by 1H nuclear magnetic resonance and mass spectrometry. Furthermore, the monooxygenase activity also
T Kuhnigk et al.
Journal of basic microbiology, 37(3), 205-211 (1997-01-01)
The capability of the intestinal flora from the gut of xylophagous termites of degrading lignin model compounds was investigated. Different dimeric lignin model compounds-degrading bacteria were obtained from the hindgut flora of Mastotermes darwiniensis Froggatt, Reticulitermes santonensis Feytaud, Nasutitermes nigriceps
W A Prütz et al.
International journal of radiation biology and related studies in physics, chemistry, and medicine, 44(2), 183-196 (1983-08-01)
Phenoxyl radicals generated pulse radiolytically by the reaction of N.3 with Gly-Tyr decay biomolecularly (2k = 4.7 X 10(8)M-1 s-1) with efficient formation of 2,2'-dimers, which enolize rapidly (k = 2.7 X 10(4) s-1) to produce the 2,2'-biphenolic product. The

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