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Key Documents

206105

Sigma-Aldrich

Ammonium tetrachloroplatinate(II)

99%

Synonym(s):

Platinum(II)-ammonium chloride

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About This Item

Linear Formula:
(NH4)2PtCl4
CAS Number:
Molecular Weight:
372.97
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23
grade:
for analytical purposes
form:
solid

grade

for analytical purposes

Assay

99%

form

solid

mp

140 °C (dec.) (lit.)

density

2.936 g/mL at 25 °C (lit.)

SMILES string

[H][N+]([H])([H])[H].[H][N+]([H])([H])[H].Cl[Pt--](Cl)(Cl)Cl

InChI

1S/4ClH.2H3N.Pt/h4*1H;2*1H3;/q;;;;;;+2/p-2

InChI key

QJIMNDWDOXTTBR-UHFFFAOYSA-L

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Application

  • Deactivation study of the hydrodeoxygenation of p-methylguaiacol: Studies catalysts prepared using ammonium tetrachloroplatinate(II), focusing on sustainable chemical processes relevant across academic research (Bouxin et al., 2017).

Features and Benefits

Reacts with creatinine (cat. no. 859702) to form various complexes such as [Pt4(creat)2Cl14]7- and [Pt4(creat)6]2- with applications in semiconductors, catalysis, mixed oxidation state studies, and electron conductivity.

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 3 Oral - Eye Dam. 1 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Season S Chen et al.
Journal of hazardous materials, 397, 122431-122431 (2020-05-22)
The structural and chemical stability of UiO-66-NH2 and its simulated solar irradiation responsive characteristic make it a suitable metal-organic framework (MOF) candidate as photocatalytic material. Platinum nanoparticles (Pt NPs) are typically immobilized in MOF to enhance the photocatalytic efficiency. However
H C Schuppe et al.
International archives of allergy and immunology, 112(2), 125-132 (1997-02-01)
The sensitizing properties of different complex salts of platinum were defined in vivo by means of the popliteal lymph node (PLN) assay in mice. Hexa- and tetrachloroplatinates were confirmed to be highly immunogenic, inducing vigorous primary immune responses in the
A case of contact hypersensitivity to platinum salts.
E Dastychová et al.
Contact dermatitis, 43(4), 226-226 (2000-09-30)
L Trynda et al.
Journal of inorganic biochemistry, 53(4), 249-260 (1994-03-01)
Absorption, CD, gel-filtration chromatography, and immunological tests were used to evaluate the interactions of K2PtCl4 with human serum albumin. Multidentate coordination of Pt(II) to HSA causes distinct variations in the protein conformation including a considerable decrease of the helical structure.
Francisco Tarazona-Vasquez et al.
The journal of physical chemistry. A, 111(5), 945-953 (2007-02-03)
Density functional theory is used to investigate the complexation ability of dendrimer outer pockets--in both tertiary amine protonated and unprotonated scenarios--toward molecular guests, particularly tetrachloroplatinate(II) and its mono- and diaquated derivatives as well as competing counterions. The effect of the

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