40559
3-Piperonylcyclobutanone
≥98.0% (HPLC)
Synonym(s):
3-(1,3-Benzodioxol-5-ylmethyl)cyclobutanone, 3-(3,4-Methylenedioxybenzyl)cyclobutanone
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About This Item
Empirical Formula (Hill Notation):
C12H12O3
CAS Number:
Molecular Weight:
204.22
MDL number:
UNSPSC Code:
12352200
PubChem Substance ID:
NACRES:
NA.25
Assay
≥98.0% (HPLC)
form
liquid
SMILES string
O=C1CC(C1)Cc2ccc3OCOc3c2
InChI
1S/C12H12O3/c13-10-4-9(5-10)3-8-1-2-11-12(6-8)15-7-14-11/h1-2,6,9H,3-5,7H2
InChI key
AWAOUJUBBHDZRM-UHFFFAOYSA-N
Application
3-Piperonylcyclobutanone may be used as a reagent in the chiral synthesis of lignan lactones such as (-)-hinokinin, (-)-deoxypodorhizone, (-)-isohibalactone and (-)-savinin.
Storage Class Code
10 - Combustible liquids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Certificates of Analysis (COA)
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Chiral synthesis of lignan lactones, (?)-hinokinin, (?)-deoxypodorhizone, (?)-isohibalactone and (?)-savinin by means of enantioselective deprotonation strategy.
Toshio Honda, Nobuaki Kimura,
Journal of the Chemical Society. Perkin Transactions 1, 1, 1043-1046 (1994)
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