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71361

Sigma-Aldrich

Sodium carbonate hydrate

purum p.a., ≥99.0% (calc. based on dry substance, T), 9-10 mol/mol water

Synonym(s):

Soda

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About This Item

Linear Formula:
Na2CO3 · aq
CAS Number:
24551-51-7
Molecular Weight:
105.99 (anhydrous basis)
EC Number:
207-838-8
MDL number:
MFCD00149178
UNSPSC Code:
12352300
PubChem Substance ID:
329763207
NACRES:
NA.21

grade

purum p.a.

Assay

≥99.0% (calc. based on dry substance, T)

form

crystals and lumps
fine crystals

impurities

9-10 mol/mol water

pH

12 (25 °C, 143 g/L)

solubility

water: soluble 142.3 g/L at 20 °C

anion traces

chloride (Cl-): ≤50 mg/kg
sulfate (SO42-): ≤50 mg/kg

cation traces

Ca: ≤50 mg/kg
Cd: ≤50 mg/kg
Co: ≤50 mg/kg
Cu: ≤50 mg/kg
Fe: ≤50 mg/kg
K: ≤100 mg/kg
Ni: ≤50 mg/kg
Pb: ≤50 mg/kg
Zn: ≤50 mg/kg

SMILES string

[Na+].[Na+].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[O-]C([O-])=O

InChI

1S/CH2O3.2Na.10H2O/c2-1(3)4;;;;;;;;;;;;/h(H2,2,3,4);;;10*1H2/q;2*+1;;;;;;;;;;/p-2

InChI key

XYQRXRFVKUPBQN-UHFFFAOYSA-L

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General description

Sodium carbonate decahydrate is a hydrated form of Na2CO3. IR spectral investigations suggest its spectra is similar to the heptahydrate form. It undergoes thermal dehydration to monohydrate form in a batch, fluidized bed reactor.

Application

Sodium carbonate decahydrate may be used to investigate the hydrolysis of poly(β-cyclodextrin-co-citric acid) (CDP, water-insoluble polymer). Polymeric hydrolysates were investigated by HPLC.

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H319

Hazard Classifications

Eye Irrit. 2

Storage Class Code

11 - Combustible Solids

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Dehydration of sodium carbonate decahydrate to monohydrate in a fluidized bed.
Hartman M, et al.
AIChE Journal, 47(10), 2333-2333 (2001)
Chemical structure of poly (β-cyclodextrin-co-citric acid).
Bednarz S, et al.
Journal of Applied Polymer Science, 119(6), 3511-3520 (2011)
An infra-red study of the hydrates of sodium carbonate.
Buijs K and Schutte CJH.
Spectrochimica Acta Part A: Molecular Spectroscopy, 17(9), 917-920 (1961)
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