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199974

Sigma-Aldrich

Aluminum oxide

activated, neutral, Brockmann I

Synonym(s):

Alumina

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About This Item

Linear Formula:
Al2O3
CAS Number:
Molecular Weight:
101.96
EC Number:
MDL number:
UNSPSC Code:
12352311
eCl@ss:
38120402
PubChem Substance ID:
NACRES:
SB.52

grade

Brockmann I
activated
standard grade

form

powder

manufacturer/tradename

CAMAG 507-C-I

technique(s)

ion chromatography: suitable

impurities

<0.03% Fe2O3
<0.03% SiO2
<0.4% Na2O

particle size

40-160 μm

pore size

58 Å pore size

pH

7.0±0.5 ( in H2O)

mp

2040 °C (lit.)

SMILES string

O=[Al]O[Al]=O

InChI

1S/2Al.3O

InChI key

TWNQGVIAIRXVLR-UHFFFAOYSA-N

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General description

The mechanism of formation of protective scales of α-Al2O3 on surfaces of binary M-Al (M = Fe, Ni or Co) alloys at high temperatures has been studied. Activated aluminum oxides having different acidities and water concentrations (having Brockmann activity I-V) can easily detect various types of water (namely free water, pore water, and bound water) on the aluminum oxide present in soils.

Application

Aluminum oxide (Alumina, Al2O3) has been used in the preparation of one-step self-assembled double-helices of multiwalled carbon nanotubes (MWCNT) arrays (composed of Fe nanoparticles bound to SiOx micro-particles).
Aluminum oxide (neutral) has been used in the preparation of alumina supported silver (Ag/Al2O3) catalyst suitable for selective catalytic reduction of nitrogen oxides (NOx) by hydrocarbons (HC-SCR).

Packaging

Brockmann aluminum oxides are suitable for column chromatography and adsorptive filtration.

Storage Class Code

13 - Non Combustible Solids

WGK

nwg

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


Certificates of Analysis (COA)

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The role of Ag O Al entities in adsorption of NCO species and reduction of NO x.
Deng H, et al.
Catalysis Today, 258, 35-40 (2015)
Carbon nanotube bundles self-assembled in double helix microstructures.
Cervantes-Sodi F, et al.
Carbon, 50(10), 3688-3693 (2012)
Thermoanalytical studies of water on activated alumina, Brockmann I-V,(acid, neutral, basic) from- 60? to+ 700? C.
Hampson JW and Bleam WF.
Thermochimica Acta, 288(1), 179-189 (1996)
Prescott R and Graham MJ.
Oxidation of Metals, 38(3-4), 233-254 (1992)
Jaakko Akola et al.
Proceedings of the National Academy of Sciences of the United States of America, 110(25), 10129-10134 (2013-06-01)
Glass formation in the CaO-Al2O3 system represents an important phenomenon because it does not contain typical network-forming cations. We have produced structural models of CaO-Al2O3 glasses using combined density functional theory-reverse Monte Carlo simulations and obtained structures that reproduce experiments

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