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90781

Sigma-Aldrich

Tributylamine

puriss. plus, ≥99.5% (GC)

Synonym(s):

Tri-n-butylamine

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About This Item

Linear Formula:
[CH3(CH2)3]3N
CAS Number:
102-82-9
Molecular Weight:
185.35
Beilstein:
1698872
EC Number:
203-058-7
MDL number:
MFCD00009431
UNSPSC Code:
12352100
PubChem Substance ID:
57653406
NACRES:
NA.21
Assay:
≥99.5% (GC)
bp:
216 °C (lit.)
vapor pressure:
0.3 mmHg ( 20 °C)
2.4 mmHg ( 55 °C)
Pricing and availability is not currently available.

vapor density

6.38 (vs air)

Quality Level

200

vapor pressure

0.3 mmHg ( 20 °C)
2.4 mmHg ( 55 °C)

grade

puriss. plus

Assay

≥99.5% (GC)

form

liquid

autoignition temp.

410 °F

expl. lim.

6 %

impurities

≤0.2% water

refractive index

n20/D 1.428 (lit.)
n20/D 1.429

bp

216 °C (lit.)

mp

−70 °C (lit.)

density

0.778 g/mL at 25 °C (lit.)

functional group

amine

SMILES string

CCCCN(CCCC)CCCC

InChI

1S/C12H27N/c1-4-7-10-13(11-8-5-2)12-9-6-3/h4-12H2,1-3H3

InChI key

IMFACGCPASFAPR-UHFFFAOYSA-N

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General description

Tributylamine is a tertiary amine. It has been reported to prevent the corrosion of mild steel in HCl solution.[1]

Application

Tributylamine (n-Bu3N) may be used in the following studies:
  • To compose the mobile phase for the liquid chromatography tandem mass spectrometry (LC-MS/MS) analysis.[2]
  • Preparation of PdCl,N and PdOAc,N (palladium nanoparticles).[3]
  • As an additive during the synthesis of 3-bromothieno[3,2-c]pyridine-4-(5H)-one.[4]

Pictograms

Skull and crossbones
GHS06

Signal Word

Danger

Hazard Statements

H302,H310 + H330,H315

Hazard Classifications

Acute Tox. 1 Inhalation - Acute Tox. 2 Dermal - Acute Tox. 4 Oral - Skin Irrit. 2

Storage Class Code

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 1

Flash Point(F)

145.4 °F - closed cup

Flash Point(C)

63 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCCL4957
BCCK7337
BCCK3512
BCCJ5273
BCCH3025

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Palladium nanoparticles obtained from palladium salts and tributylamine in molten tetrabutylammonium bromide: their use for hydrogenolysis-free hydrogenation of olefins.
Le Bras J, et al.
New. J. Chem., 28(12), 1550-1553 (2004)
Tributylamine as corrosion inhibitor for mild steel in hydrochloric acid.
Bastidas JM, et al.
J. Mater. Sci., 35(11), 2637-2642 (2000)
Thermal Synthesis of 3-Bromothieno [3, 2-c] pyridin-4-(5H)-one: A Telescoped Procedure with Tributylamine.
Boros EE and Kaldor I.
Journal of Heterocyclic Chemistry, 52(1), 302-305 (2015)
Alexander S Misharin et al.
Analytical chemistry, 77(2), 459-470 (2005-01-15)
The analytical performance of an atmospheric pressure sampling, multiple-channel, high-throughput mass spectrometer was investigated using samples of a variety of types. The instrument, based on an array of cylindrical ion traps, was built with four independent channels and here is
Christopher J Jones et al.
Journal of chromatography. A, 1217(4), 479-488 (2009-12-17)
Reverse-phase ion-pair high performance liquid chromatography (RPIP-HPLC) and ultra-performance liquid chromatography (RPIP-UPLC) are increasingly popular chromatographic techniques for the separation of organic compounds. However, the fine details of the RPIP separation mechanism are still being debated. Many factors including type
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