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795615

Sigma-Aldrich

Pentamethylcyclopentadienyl cyclopentadienyl rhodium dimer

Synonym(s):

1,1,1,1,1-Pentamethylrhodocene dimer, [RhCp*Cp]2

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About This Item

Empirical Formula (Hill Notation):
C30H40Rh2
Molecular Weight:
606.45
UNSPSC Code:
12352103
PubChem Substance ID:
329768497

form

solid

Quality Level

100

storage temp.

−20°C

SMILES string

C[C]1[C](C)[C](C)[C](C)[C]1C.CC2=C(C)C(C)=C(C)C2(C)C3C=CC=C3.[C]4[C][C][C][C]4.[Rh].[Rh]

InChI

1S/C15H20.C10H15.C5H5.2Rh/c1-10-11(2)13(4)15(5,12(10)3)14-8-6-7-9-14;1-6-7(2)9(4)10(5)8(6)3;1-2-4-5-3-1;;/h6-9,14H,1-5H3;1-5H3;1-5H;;

InChI key

WQFYUUJDMAQBRZ-UHFFFAOYSA-N

Application

Used as n-dopant

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Production of heavily n- and p-doped CVD graphene with solution-processed redox-active metal?organic species
Paniagua, S. A.;
Materials Horizons, 1, 111-111 (2014)
n-Doping of Organic Electronic Materials Using Air-Stable Organometallics: A Mechanistic Study of Reduction by Dimeric Sandwich Compounds
Guo, S.;
Chemistry (Weinheim An Der Bergstrasse, Germany), 18, 14760-14760 (2012)
Song Guo et al.
Advanced materials (Deerfield Beach, Fla.), 24(5), 699-703 (2011-11-08)
Air-stable dimers of sandwich compounds including rhodocene and (pentamethylcyclopentadienyl)(arene)ruthenium and iron derivatives can be used for n-doping electron-transport materials with electron affinities as small as 2.8 eV. A p-i-n homojunction diode based on copper phthalocyanine and using rhodocene dimer as

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