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744441

5-Chloro-5H-dibenzo[a,d]cycloheptene

Name: 5-Chloro-5<I>H</I>-dibenzo[<I>a,d</I>]cycloheptene
Brand: ALDRICH

97%

Synonym(s):

5H-Dibenzo[a,d]cyclohepten-5-yl chloride, Dibenzosuberenyl chloride, tropCl

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About This Item

Empirical Formula (Hill Notation):

C₁₅H₁₁Cl

CAS Number:

18506-04-2

Molecular Weight:

226.70

Beilstein:

515093

MDL number:

MFCD26143082

UNSPSC Code:

12352300

PubChem Substance ID:

329765693

Assay

≥96.5% (HPLC)
97%

form

powder

SMILES string

ClC1C(C=CC=C2)=C2C=CC3=C1C=CC=C3

InChI

1S/C15H11Cl/c16-15-13-7-3-1-5-11(13)9-10-12-6-2-4-8-14(12)15/h1-10,15H

InChI key

XUDMFUCJNFYMRZ-UHFFFAOYSA-N

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

Pictograms

GHS09

Signal Word

Warning

Hazard Statements

H410

Precautionary Statements

P273 - P501

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Ethanol as hydrogen donor: highly efficient transfer hydrogenations with rhodium(I) amides.

Theo Zweifel et al.

Angewandte Chemie (International ed. in English), 47(17), 3245-3249 (2008-03-19)

Amine olefin rhodium(I) complexes: pKa and NH bond strength.

Torsten Büttner et al.

Chemical communications (Cambridge, England), 24(24), 2820-2821 (2004-12-16)

A combination of the rigid bis(5H-dibenzo[a,d]cyclohepten-5-yl)amine (trop(2)NH) and 5-amino-5H-dibenzo[a,d]cycloheptene (tropNH(2)) ligand allowed the synthesis of the stable pentacoordinated 18 electron amine olefin rhodium(i) complex [Rh(trop(2)NH)(tropNH(2))]O(3)SCF(3)(); this complex can be cleanly deprotonated [pK(a)(DMSO) = 20.6(1)] to the corresponding amide [Rh(trop(2)N)(tropNH(2))](6) which

Electromeric rhodium radical complexes.

Florian Frank Puschmann et al.

Angewandte Chemie (International ed. in English), 49(2), 385-389 (2009-12-04)

Chiral Rhodium(I) and Iridium(I) Amino-Olefin Complexes:? pKa, N-H Bond Dissociation Energy, and Catalytic Transfer Hydrogenation

Maire, P., et al.

Organometallics, 24, 3207-3218 (2005)

Catalyzed Dehydrogenative Coupling of Primary Alcohols with Water, Methanol, or Amines

Zweifel, T., et al.

Angewandte Chemie (International Edition in English), 49, 559-563 (2009)

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