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Sigma-Aldrich

Takasago (R)-Ru Cymene Kit I

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About This Item

UNSPSC Code:
12352000
NACRES:
NA.22

storage temp.

2-8°C

General description

Takasago (R)-Ru Cymene Kit I comprises of ruthenium-based biphenyl phosphine cymene catalysts containing either BINAP and SEGPHOS® ligands. These highly reactive and selective catalysts are useful in a variety of asymmetric reactions, mainly asymmetric hydrogenation.

Legal Information

Sold in collaboration with Takasago for research purposes only.
SEGPHOS is a registered trademark of Takasago Intl. Corp.

Kit Components Only

Product No.
Description
  • (R)-RuCl[(p-cymene)(T-BINAP)]Cl 100 mg

Kit Components Also Available Separately

Product No.
Description
SDS
  • 692409(R)−RuCl[(p−cymene)(DM−BINAP)]Cl 50 mgSDS
  • 692417(R)-RuCl[(p-cymene)(DM-SEGPHOS®)]Cl 50 mgSDS
  • 692425(R)-RuCl[(p-cymene)(DTBM-SEGPHOS®)]Cl 50 mgSDS
  • 692492(R)-RuCl[(p-cymene)(BINAP)]Cl 100 mgSDS
  • 692514(R)-RuCl[p-cymene)(H8-BINAP)]Cl 50 mgSDS
  • 692522(R)−RuCl[(p−cymene)(SEGPHOS®)]Cl 50 mgSDS

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Ryoji Noyori et al.
Angewandte Chemie (International ed. in English), 40(1), 40-73 (2001-02-13)
Hydrogenation is a core technology in chemical synthesis. High rates and selectivities are attainable only by the coordination of structurally well-designed catalysts and suitable reaction conditions. The newly devised [RuCl(2)(phosphane)(2)(1,2-diamine)] complexes are excellent precatalysts for homogeneous hydrogenation of simple ketones

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