The Journal of organic chemistry, 68(12), 4631-4642 (2003-06-07)
Representative organoborane mixtures were quantitatively converted to their borohydrides through their reaction with activated KH (KH), permitting their detailed analysis by (11)B NMR. Through the treatment of commercial KH with a THF solution of lithium aluminum hydride (LAH), a dramatic
A new atomizer based on atmospheric pressure dielectric barrier discharge (DBD) plasma was specially designed for atomic fluorescence spectrometry (AFS) in order to be applied to the measurement of arsenic. The characteristics of the DBD atomizer and the effects of
Room-temperature ionic liquid in combination with sodium diethyldithiocarbamate (DDTC) was used to synergetically improve the chemical vapor generation (CVG) of nickel. Volatile species of nickel were effectively generated through reduction of acidified analyte solution with KBH(4) in the presence of
The Journal of biological chemistry, 261(25), 11538-11543 (1986-09-05)
Bacterial 5-oxoprolinase is composed of two protein components: Component A, which catalyzes 5-oxoproline-dependent ATP-hydrolysis and Component B, which couples the hydrolysis of ATP with the decyclization of 5-oxoproline to form glutamate (Seddon, A. P., Li, L., and Meister, A. (1984)
Reduction with [3H]KBH4 of Schiff's bases generated by reaction with pyridoxal 5'-phosphate (which cannot penetrate the intact cytoplasmic membrane) yields tritium-labeled derivatives of both proteins and lipids accessible on the periplasmic side of the cytoplasmic membrane. Application of this technique
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