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Sigma-Aldrich

Samarium(III) isopropoxide

99.9% trace metals basis

Synonym(s):

Samarium triisopropoxide, Tris(isopropoxy)samarium

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About This Item

Linear Formula:
Sm[OCH(CH3)2]3
CAS Number:
3504-40-3
Molecular Weight:
327.62
MDL number:
MFCD00058820
UNSPSC Code:
12352103
PubChem Substance ID:
24865693
NACRES:
NA.23

Assay

99.9% trace metals basis

form

powder and chunks

reaction suitability

core: samarium
reagent type: catalyst

SMILES string

CC(C)O[Sm](OC(C)C)OC(C)C

InChI

1S/3C3H7O.Sm/c3*1-3(2)4;/h3*3H,1-2H3;/q3*-1;+3

InChI key

HJCRVWSKQNDSPZ-UHFFFAOYSA-N

Application

Used with a dinucleating Schiff base ligand in a catalytic asymmetric nitro-Mannich reaction.

Pictograms

FlameExclamation mark
GHS02,GHS07

Signal Word

Warning

Hazard Statements

H228,H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Flam. Sol. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

4.1B - Flammable solid hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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syn-Selective catalytic asymmetric nitro-Mannich reactions using a heterobimetallic Cu-Sm-Schiff base complex.
Shinya Handa et al.
Journal of the American Chemical Society, 129(16), 4900-4901 (2007-03-31)

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