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195332

Sigma-Aldrich

1-Bromotetradecane

97%

Synonym(s):

Myristyl bromide, Tetradecyl bromide

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About This Item

Linear Formula:
CH3(CH2)13Br
CAS Number:
112-71-0
Molecular Weight:
277.28
Beilstein:
1742640
EC Number:
203-999-3
MDL number:
MFCD00000228
UNSPSC Code:
12352100
PubChem Substance ID:
24851686
NACRES:
NA.22

Assay

97%

form

liquid

refractive index

n20/D 1.460 (lit.)

bp

175-178 °C/20 mmHg (lit.)

mp

5-6 °C (lit.)

density

0.932 g/mL at 25 °C (lit.)

SMILES string

CCCCCCCCCCCCCCBr

InChI

1S/C14H29Br/c1-2-3-4-5-6-7-8-9-10-11-12-13-14-15/h2-14H2,1H3

InChI key

KOFZTCSTGIWCQG-UHFFFAOYSA-N

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Application

1-Bromotetradecane was used in the synthesis of:
  • tetradecylferrocene
  • cationic and zwitterionic gemini surfactants
  • metallomesogenic polymers based on bis[η1(N)-3,4-dialkyloxybenzylidene-4′-dodecyloxyaniline]dichloropalladium(II) with octyl, decyl, dodecyl, tetradecyl and hexadecyl alkyl groups
  • 9-tetradecylcarbazole

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

235.4 °F - closed cup

Flash Point(C)

113 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Katrin Wedeking et al.
Langmuir : the ACS journal of surfaces and colloids, 22(7), 3161-3165 (2006-03-22)
Tetradecylferrocene (4, Fc-(CH2)13CH3) was synthesized via lithiation of ferrocene by treatment with tert-butyl lithium, followed by alkylation with 1-bromotetradecane. Complex 4 forms a physisorbed ordered molecular monolayer on the surface of highly oriented pyrolytic graphite (HOPG) that was analyzed by
Novel Metallomesogenic Polymers Derived from ? 1-Benzylideneaniline Palladium (II) Complex.
Lee M, et al.
Macromolecules, 32(8), 2777-2782 (1999)
R Hernández-Bravo et al.
The journal of physical chemistry. B, 122(15), 4325-4335 (2018-03-29)
A combined study for understanding the molecular interactions of asphaltenes with molecular species such as ionic liquids (ILs) comprised experimental measurements and computational numerical simulation calculations, using density-functional theory (DFT) with dispersion corrections, molecular dynamics (MD) calculations, and experimental rheological
Atakilt Abebe et al.
Bioinorganic chemistry and applications, 2018, 8097483-8097483 (2018-08-18)
New organic salts were synthesized by quaternizing 1,10-phenanthroline using 1-bromotetradecane. The first step yielded an organic salt of formula [C26H37N2]Br. Anion exchange reaction using Li[(CF3SO2)2N] resulted in a more stable salt of formula [C26H37N2][(CF3SO2)2N]. The organic salts were investigated by
Nusrat Jahan et al.
The Journal of organic chemistry, 74(20), 7762-7773 (2009-09-18)
Simple strategies for the synthesis of five series of cationic gemini surfactants and one series of zwitterionic gemini surfactants from pentaerythritol have been developed. Two lipophilic groups were introduced onto pentaerythritol by alkylation of the known compound, O-benzylidenepentaerythritol, with 1-bromooctane
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